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Effect of sulfate ion adsorption on the rate of copper electrocrystallization on Ag(111) face

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Abstract

The process of copper electrocrystallization on the Ag(111) face was studied in acidic perchlorate-sulfate electrolytes. Enhanced rate of charge transfer in the course of nucleation and growth of epitaxial copper crystallites was observed in the solutions with additives of sulfate ion as a result of local electrostatic effects under specific adsorption of anions. Copper nucleation parameters were estimated in the framework of the diffusion models and atomistic theory of electrochemical nucleation.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    M. R. Ehrenburg, A. A. Rybin & A. I. Danilov

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  1. M. R. Ehrenburg
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  2. A. A. Rybin
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  3. A. I. Danilov
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Correspondence to A. I. Danilov.

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Original Russian Text © M.R. Ehrenburg, A.A. Rybin, A.I. Danilov, 2010, published in Elektrokhimiya, 2010, Vol. 46, No. 6, pp. 761–768.

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Ehrenburg, M.R., Rybin, A.A. & Danilov, A.I. Effect of sulfate ion adsorption on the rate of copper electrocrystallization on Ag(111) face. Russ J Electrochem 46, 714–720 (2010). https://doi.org/10.1134/S1023193510060170

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  • DOI: https://doi.org/10.1134/S1023193510060170

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