Skip to main content
SpringerLink
Log in

Solid rubidium-conducting electrolytes in Rb1 − 2x Me x AlO2 systems (Me = Pb, Cd, Ca)

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

New highly conducting rubidium cationic solid electrolytes were synthesized on the basis of rubidium aluminates by partial substitution of Rb+ cations with Pb2+, Cd2+, and Ca2+ divalent ions and studied. All these three additives essentially increase electroconductivity of RbAlO2 especially in the low-temperature range. The values of electroconductivity and its activation energy are close for the optimum compositions in three studied systems. The conductivity of rubidium monoaluminate is increased by the studied additives due to formation of additional rubidium vacancies by substitution 2 Rb+ → Me2+ + V′Rb.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Burmakin, E.I., Tverdye elektrolity s provodimost’yu po kationam shchelochnykh metallov (Solid Electrolytes Conducting by Alkali Metal Cations), Moscow: Nauka, 1992.

    Google Scholar 

  2. Ivanov-Shits, A.K. and Murin, I.V., Ionika tverdogo tela (Solid State Ionics), St. Petersburg: SPbU, 2000.

    Google Scholar 

  3. Burmakin, E.I. and Shekhtman, G.Sh., Elektrokhimiya, 1988, vol. 24, p. 383.

    CAS  Google Scholar 

  4. Burmakin, E.I., Smol’nikov, V.V., Shekhtman, G.Sh., and Korovenkova, E.S., Elektrokhimiya, 1990, vol. 26, p. 1528.

    CAS  Google Scholar 

  5. Burmakin, E.I., Smol’nikov, V.V., Shekhtman, G.Sh., and Korovenkova, E.S., Elektrokhimiya, 1992, vol. 28, p. 947.

    CAS  Google Scholar 

  6. Smol’nikov, V.V., Burmakin, E.I., and Shekhtman, G.Sh., X Vsesoyuz. konf. po fiz. khimii i elektrokhimii ionnykh rasplavov i tverdykh elektrolitov. Tez. dokl. (X All-Union Conference on Physical Chemistry and Electrochemistry of Ionic Melts and Solid Electrolytes. Abstracts, Yekaterinburg: UrO RAN, 1992, vol. 3, p. 113.

    Google Scholar 

  7. Shekhtman, G.Sh., Volegova, E.I., and Burmakin, E.I., XIV Rossiiskaya konf. po fiz. khimii i elektrokhimii rasplavlennykh i tverdykh elektrolitov. Tez. dokl. (XIV Russian Conference on Physical Chemistry and Electrochemistry of Molten and Solid Electrolytes. Abstracts, Yekaterinburg: UrO RAN, 2007, vol. 2, p. 155.

    Google Scholar 

  8. Shekhtman, G.Sh., Volegova, E.I., and Burmakin, E.I., Elektrokhimiya, 2009, vol. 45, p. 495 [Russ. J. Electrochem. (Engl. Transl.), vol. 45, p. ].

    Google Scholar 

  9. Langlet, G., C. R. Acad. Sci., 1964, vol. T. 259, p. 103.

    Google Scholar 

  10. Burmakin, E.I., Burov, G.V., Rozanov, I.G., and Shekhtman, G.Sh., Zh. Neorg. Khim., 1978, vol. 23, p. 3366.

    CAS  Google Scholar 

  11. Burmakin, E.I., Shekhtman, G.Sh., and Zhidovinova, S.V., Zh. Neorg. Khim., 1985, vol. 30, p. 2228.

    CAS  Google Scholar 

  12. Burmakin, E.I., Voronin, V.I., Akhtyamova, L.Z., Berger, I.F., and Shekhtman, G.Sh., Elektrokhimiya, 2005, vol. 41, p. 878 [Russ. J. Electrochem. (Engl. Transl.), vol. 41, p. ].

    Google Scholar 

  13. Shannon, R.D., Acta Crystallogr., 1976, vol. A32, p. 751.

    CAS  Google Scholar 

  14. Irvine, J.T.S. and West, A.R., Mater. Res. Bull., 1987, vol. 22, p. 1047.

    Article  CAS  Google Scholar 

  15. Ukshe, E.A. and Bukun, N.G., Tverdye elektrolity (Solid Electrolytes), Moscow: Nauka, 1977.

    Google Scholar 

  16. Chebotin, V.N. and Perfil’ev, M.V., Elektrokhimiya tverdykh elektrolitov (The Electrochemistry of Solid Electrolytes), Moscow: Khimiya, 1978.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi 22, Yekaterinburg, 620219, Russia

    E. I. Burmakin, E. I. Volegova, B. D. Antonov & G. Sh. Shekhtman

Authors
  1. E. I. Burmakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. I. Volegova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. D. Antonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. Sh. Shekhtman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. I. Burmakin.

Additional information

Original Russian Text © E.I. Burmakin, E.I. Volegova, B.D. Antonov, G.Sh. Shekhtman, 2010, published in Elektrokhimiya, 2010, Vol. 46, No. 5, pp. 599–604.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Burmakin, E.I., Volegova, E.I., Antonov, B.D. et al. Solid rubidium-conducting electrolytes in Rb1 − 2x Me x AlO2 systems (Me = Pb, Cd, Ca). Russ J Electrochem 46, 565–570 (2010). https://doi.org/10.1134/S1023193510050113

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193510050113

Key words

Search

Navigation