Skip to main content
SpringerLink
Log in

Modified model of electrical double layer for mixed solutions of constant ionic strength

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

A model is suggested, which generalized the Alekseev-Popov-Kolotyrkin model for the case of mixed solutions of constant ionic strength of the type mc KA −* + (1 − m)c KA, where A −* is the surface-active anion that lowers the electrical double layer capacitance as compared with that observed in the presence of surface-inactive anion A−. Calculations made for a real system mc NaNO3 + (1 − m)c NaF showed that at 0.2 ≤ m ≤ 1 a transition occurred from quadratic to linear dependence of adsorption energy on the electrode potential (or charge). The conclusions are in agreement with experimental data obtained for the studied system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Payne, R., J. Phys. Chem., 1965, vol. 69, p. 4113.

    Article  CAS  Google Scholar 

  2. Payne, R., J. Electrochem. Soc., 1966, vol. 113, p. 999.

    Article  CAS  Google Scholar 

  3. Payne, R., J. Phys. Chem., 1966, vol. 70, p. 204.

    Article  CAS  Google Scholar 

  4. Grahame, D.C. and Parsons, R., J. Am. Chem. Soc., 1961, vol. 83, p. 1291.

    Article  CAS  Google Scholar 

  5. Grahame, D.C., J. Am. Chem. Soc., 1958, vol. 80, p. 4201.

    Article  CAS  Google Scholar 

  6. Dutkiewicz, E. and Parsons, R., J. Electroanal. Chem., 1966, vol. 11, p. 100.

    Article  CAS  Google Scholar 

  7. Damaskin, B.B., Perchenko, O.A., and Karpov, S.I., Elektrokhimiya, 1985, vol. 21, p. 103.

    CAS  Google Scholar 

  8. Damaskin, B.B. and Perchenko, O.A., Elektrokhimiya, 1985, vol. 21, p. 324.

    CAS  Google Scholar 

  9. Perchenko, O.A. and Damaskin, B.B., Elektrokhimiya, 1985, vol. 21, p. 1459.

    CAS  Google Scholar 

  10. Alekseev, Yu.V., Popov, Yu.A., and Kolotyrkin, Ya.M., J. Electroanal. Chem., 1975, vol. 62, p. 135.

    Article  Google Scholar 

  11. Frumkin, A.N., Z. Phys. Chem. (Munich), 1925, vol. 116, p. 466.

    CAS  Google Scholar 

  12. Damaskin, B.B. and Karpov, S.I., Elektrokhimiya, 1982, vol. 18, p. 3.

    CAS  Google Scholar 

  13. Damaskin, B.B., Karpov, S.I., and Dyatkina, S.L., Elektrokhimiya, 1982, vol. 18, p. 261.

    CAS  Google Scholar 

  14. Damaskin, B., Karpov, S., Dyatkina, S., Palm, U., and Salve, M., J. Electroanal. Chem., 1985, vol. 189, p. 183.

    Article  CAS  Google Scholar 

  15. Grahame, D.C., Chem. Rev., 1947, vol. 41, p. 441.

    Article  CAS  Google Scholar 

  16. Frumkin, A.N., Z. Phys., 1926, vol. 35, p. 792.

    Article  CAS  Google Scholar 

  17. Damaskin, B.B., Petrii, O.A., and Batrakov, V.V., Adsorbtsiya organicheskikh soedinenii na elektrodakh (Adsorption of Organic Substances on Electrodes), Moscow: Nauka, 1968.

    Google Scholar 

  18. Damaskin, B.B., Baturina, O.A., and Safonov, V.A., Elektrokhimiya, 2000, vol. 36, p. 1319 [Russ. J. Electrochem. (Engl. Transl.), vol. 36, p. ].

    Google Scholar 

  19. Damaskin, B.B., Elektrokhimiya, 2008, vol. 44, p. 373 [Russ. J. Electrochem. (Engl. Transl.), vol. 44, p. ].

    Google Scholar 

  20. De Levi, R., J. Electrochem. Soc., 1971, vol. 118, p. 185.

    Article  Google Scholar 

  21. Damaskin, B.B. and Pankratova, I.A., Elektrokhimiya, 1987, vol. 23, p. 523.

    CAS  Google Scholar 

  22. Damaskin, B.B., J. Electroanal. Chem., 1975, vol. 65, p. 799.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University, Moscow, 119991, Russia

    B. B. Damaskin, E. V. Stenina & L. N. Sviridova

Authors
  1. B. B. Damaskin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Stenina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. N. Sviridova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. B. Damaskin.

Additional information

Original Russian Text © B.B. Damaskin, E.V. Stenina, L.N. Sviridova, 2010, published in Elektrokhimiya, 2010, Vol. 46, No. 4, pp. 395–403.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Damaskin, B.B., Stenina, E.V. & Sviridova, L.N. Modified model of electrical double layer for mixed solutions of constant ionic strength. Russ J Electrochem 46, 374–382 (2010). https://doi.org/10.1134/S1023193510040026

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193510040026

Key words

Search

Navigation