Abstract
The impedance spectra of CeF3/CeF3 bicrystal (two single crystals separated by a single intercrystalline boundary) between Ag-electrodes are studied over a 135 to 410 K temperature interval (including temperatures below room temperature). The bicrystal was prepared by thermal-diffusion welding under a pressure of 1.5 × 107 Pa at 1473 K in vacuum (∼10−2 Pa). It is shown that the intercrystalline boundary affects but insignificantly the bicrystal bulk impedance. The CeF3/CeF3 ionic conductivity is 3 × 10−6 S/cm at 293 K; it is mainly determined by transfer processes in the single crystal bulk.
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Original Russian Text © N.I. Sorokin, B.P. Sobolev, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 11, pp. 1398–1402.
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Sorokin, N.I., Sobolev, B.P. The impedance of the Ag-CeF3/CeF3 bicrystal-Ag system. Russ J Electrochem 45, 1296–1299 (2009). https://doi.org/10.1134/S1023193509110111
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DOI: https://doi.org/10.1134/S1023193509110111