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Spherical and cylindrical inert electrode/solid electrolyte interface charging kinetics

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Abstract

The inert electrode/solid electrolyte interface charging kinetics in the cases of spherical and cylindrical electrode was studied by the operation impedance method in two modes (pulse galvanostatic and pulse potentiostatic). The considered case of slow diffusion and adsorption-desorption of the minor carriers (rigid sublattice defects) of solid electrolyte is true for relatively long charging time of the studied interface. The comparative analysis involved the derived potential-time and current-time kinetic relationships and similar earlier expressions for plane inert electrode.

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Authors and Affiliations

  1. Dagestan State Pedagogical University, 57 M. Yaragskogo ul., Makhachkala, 367003, Russia

    R. M. Guseinov

  2. Branch of M.D. Millionshchikov State Oil Institute in Groznyy, Vokzal’naya ul. 54, Derbent, 368600, Russia

    M. R. Karibov

Authors
  1. R. M. Guseinov
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  2. M. R. Karibov
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Correspondence to R. M. Guseinov.

Additional information

Original Russian Text © R.M. Guseinov, M.R. Karibov, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 10, pp. 1293–1296.

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Guseinov, R.M., Karibov, M.R. Spherical and cylindrical inert electrode/solid electrolyte interface charging kinetics. Russ J Electrochem 45, 1198–1201 (2009). https://doi.org/10.1134/S1023193509100140

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  • DOI: https://doi.org/10.1134/S1023193509100140

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