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Electrochemical study of Au(III)-luteolin flavonoid system in tris-buffer

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Abstract

The Au(III)-luteolin system was studied by means of cyclic voltammetry, spectrometry, and quantum chemical simulation. The mutual effect of luteolin to Au(III) reduction and Au(III) to luteolin oxidation was studied by means of cyclic voltammetry on Pt and carbon glass electrodes in 0.05 M tris-buffer solution (pH 8) containing ethyl alcohol. The absorption spectra of luteolin were recorded with and without Au(III) in 0.05 M tris-buffer solution (pH 8) containing ethyl alcohol. The quantum chemical simulation of Au(III)-tris, Au(III)-luteolin, and Au(III)-tris-luteolin systems was carried out. On the basis of the collected data, formation of Au(III)-tris-luteolin complex in 0.05 M tris-buffer solution (pH 8) in the presence of ethanol was suggested.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia

    S. I. Kulakovskaya, L. A. Levchenko, A. P. Sadkov, N. G. Lobanova & A. F. Shestakov

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  1. S. I. Kulakovskaya
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  2. L. A. Levchenko
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  3. A. P. Sadkov
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  4. N. G. Lobanova
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  5. A. F. Shestakov
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Correspondence to S. I. Kulakovskaya.

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Original Russian Text © S.I. Kulakovskaya, L.A. Levchenko, A.P. Sadkov, N.G. Lobanova, A.F. Shestakov, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 10, pp. 1221–1231.

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Kulakovskaya, S.I., Levchenko, L.A., Sadkov, A.P. et al. Electrochemical study of Au(III)-luteolin flavonoid system in tris-buffer. Russ J Electrochem 45, 1135–1144 (2009). https://doi.org/10.1134/S1023193509100048

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  • DOI: https://doi.org/10.1134/S1023193509100048

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