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Conductivity of molten LiF-ZrF4, NaF-ZrF4, KF-ZrF4, RbF-ZrF4, and CsF-ZrF4 systems

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Abstract

Specific conductivity of molten salt mixtures of the LiF-ZrF4, NaF-ZrF4, KF-ZrF4, RbF-ZrF4, and CsF-ZrF4 systems is measured in the whole concentration range using the reference capillary technique. The results are presented in the form of equations of the χ = a + bT + cT 2 [S m−1] type. The concentration dependences of molar conductivity are calculated on the basis of the density data. The obtained regularities are explained in the terms of the complex model of ion melt structures.

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Authors and Affiliations

  1. State Educational Institution “Ural State Technical University UPI”, ul. Mira 19, 620002, Ekaterinburg, Russia

    S. F. Katyshev & L. M. Teslyuk

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  1. S. F. Katyshev
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  2. L. M. Teslyuk
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Correspondence to S. F. Katyshev.

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Original Russian Text © S.F. Katyshev, L.M. Teslyuk, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 7, pp. 884–888.

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Katyshev, S.F., Teslyuk, L.M. Conductivity of molten LiF-ZrF4, NaF-ZrF4, KF-ZrF4, RbF-ZrF4, and CsF-ZrF4 systems. Russ J Electrochem 45, 823–827 (2009). https://doi.org/10.1134/S1023193509070192

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  • DOI: https://doi.org/10.1134/S1023193509070192

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