Abstract
The method of cyclic voltammetry was used to study cathodic processes in a molten salt of NaCl-KCl-NaF (10 wt %)-K2HfF6-K2SiF6. The parameters of electrochemical synthesis allowing synthesizing hafnium silicides are determined and hafnium silicide HfSi2 is obtained using galvanostatic electrolysis.
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Samsonov, G.V. and Vinitskii, I.M., Tugoplavkie soedineniya (The Refractory Compounds), Moscow: Metallurgiya, 1976.
Kun, A.T., Elektrokhimiya. Proshedshie tridtsat’ i budushchie tridtsat’ let (Electrochemistry. The Past Thirty and Future Thirty Years), Blum, G. and Gutman, F., Eds., Moscow: Khimiya, 1982, p. 108.
Murarka, S.P. and Chang, C.C., Appl. Phys. Lett., 1980, vol. 37, p. 639.
Kircher, C.J., Mayer, J.W., Tu, K.N., and Ziegler, J.F., Appl. Phys. Lett., 1973, vol. 22, p. 81.
So, F.C.T., Lien, C.-D., and Nicolet, M.-A., J. Vac. Sci. Technol., 1985, vol. A3, p. 2284.
Lin, M.-H. and Chiou, S.-Y., Jpn. J. Appl. Phys., 2004, vol. 43, p. 3340.
Johnson-Steigelman, H.T., Brinck, A.V., Parihar, S.S., and Lyman, P.F., Phys. Rev., 2004, vol. 69, p. 235.
Kuznetsov, S.A., Doctoral (Chem.) Dissertation, Yekaterinburg: IVTE, 1993.
Shunk, F.A., Constitution of Binary Alloys: The Second Supplement, New York: McGraw-Hill, 1966.
Kuznetsov, S.A, in Molten Salts: From Fundamentals to Application, Gaune-Escard, M., Ed., Norwell, MA: Kluwer, Academ. Publ., 2002, vol. 52, p. 283.
Kuznetsov, S.A. and Gaune-Escard, M., J. Electroanal. Chem., 2006, vol. 595, p. 11.
Kuznetsov, S.A., Polyakov, E.G., Kuznetsova, S.V., and Stangrit, P.T., Zh. Prikl. Khim., 1988, vol. 61, p. 160.
Kuznetsova, S.V., Dolmatov, V.S., and Kuznetsov, S.A., Elektrokhimiya, 2009, vol. 45, no. 7 [Russ. J. Elektrochem. (Engl. Transl.), vol. 45, no. 7].
Kuznetsov, S.A., Kuznetsova, S.V., Polyakov, E.G., and Stangrit, P.T., Rasplavy, 1988, vol. 2, p. 110.
Nicholson, R.S. and Shain, I., Anal. Chem., 1964, vol. 36, p. 706.
Golovin, V.A. and Dobren’kov, G.L., Trudy Kazan. Khim-Tekhnol. In-Ta, 1965, vol. 34, p. 202.
Matsuda, H. and Ayabe, Y., Z. Electrochem., 1955, vol. 59, p. 494.
Delahay, P., New Instrumental Methods in Electrochemistry: Theory, Instrumentation, and Application to Analytical and Physical Chemistry, New York: Interscience, 1954.
Baraboshkin, A.N., Elektrokristallizatsiya metallov iz rasplavlennykh solei (Electrocrystallization of Metals from Molten Salts), Moscow: Nauka, 1976.
Heyrovsky, J. and Kuta, J., Zaklady Polarografie, Prague: Nakl. eskoslovenske Akad. Ved., 1965.
Delimarskii, Yu.K., Elektrokhimiya ionnykh rasplavov (The Electrochemistry of Ionic Melts), Moscow: Metallurgiya, 1978.
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Original Russian Text © S.V. Kuznetsova, S.A. Kuznetsov, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 7, pp. 804–810.
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Kuznetsova, S.V., Kuznetsov, S.A. Electrochemical synthesis of hafnium silicides. Russ J Electrochem 45, 749–755 (2009). https://doi.org/10.1134/S1023193509070064
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DOI: https://doi.org/10.1134/S1023193509070064