Abstract
The results of studies of solid solutions with the overall composition of Bi4V2 − x Ge x O11 − δ and Bi4Ge3 − x V x O12 + δ are presented. The process of phase formation are studied during the synthesis of solid solution using the ceramic method and through liquid precursors. Crystallochemical parameters of the obtained compounds are determined. The size distribution of the particles is studied. Conductivity of annealed of polycrystalline samples as a function of temperature and composition is studied using the impedance spectroscopy method. The shape of impedance complex plane plots of the samples obtained in different ways is studied and analyzed.
Similar content being viewed by others
References
Paydar, M.H., Hadian, A.M., and Fafilek, G., J. Europ. Ceramic Soc., 2001, vol. 21, p. 1821.
Zyryanov, V.V., Neorgan. Mater., 2005, vol. 41, no. 2, p. 201.
Rez, I.S., Usp. Fiz. Nauk, 1967, vol. 93, no. 4, p. 633.
Buyanova, E.S., Zhukovskii, V.M., Lopatina, E.S., Ivanovskaya, V.V., and Raitenko, E.A., Neorgan. Mater., 2002, vol. 38, no. 3, p. 325.
Shannon, R.D. and Prewitt, C.T., Acta Crystallogr., 1969, vol. 25, p. 925.
Raengthon, N., et al., Curr. Appl. Phys., 2007. doi: 10.1016/j.cap.2007.07.002.
Emel’yanova, Yu.V., Salimgareeva, Zh.V., Buyanova, E.S., and Zhukovskii, V.M., Neorgan. Mater., 2005, vol. 41, no. 10, p. 1254.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.V. Emel’yanova, M.V. Morozova, Z.A. Mikhailovskaya, E.V. Velichko, E.S. Buyanova, V.M. Zhukovskii, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 4, pp. 407–412.
Rights and permissions
About this article
Cite this article
Emel’yanova, Y.V., Morozova, M.V., Mikhailovskaya, Z.A. et al. Synthesis processes and transport properties of solid solutions in the Bi2O3-GeO2-V2O5 system. Russ J Electrochem 45, 382–387 (2009). https://doi.org/10.1134/S1023193509040041
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193509040041