Abstract
A comparative study of the sorption effect is performed for nitrogen-containing ammonium, phenylammonium (PhA+), and tetrabutylammonium (TBA+) cations on conducting and hydrophilic properties of protonic form of perfluorinated sulfocationite MF-4SC membrane. Conductometric method was used to study thermodynamic equilibria in the systems of perfluorinated MF-4SC membrane—aniline in the acid solutions of variable composition (PhA+/HCl and PhA+/H2SO4). Concentration constants of ion-exchange equilibrium are calculated for a MF-4SC membrane on the basis of these data. These constants in the solutions of aniline with HCl and H2SO4 are 10.3 and 27.0, accordingly. The choice of sulfuric acid as background electrolyte for matrix polyaniline synthesis is substantiated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Pul, Ch. and Ouens, F., Nanotekhnologii (Nanotechnologies), Moscow: Tekhnosfera, 2005.
Tarasevich, M.R., Orlov, F.B., Shkol’nikov, E.I., et al., Electrokhimiya polimerov (Electrochemistry of Polymers), Moscow: Nauka, 1990.
Timonov, A.M. and Vasil’eva, S.V., Sorosovskii Obrazovatel’nyi Zhurnal, 2000, vol. 6, no. 3, p. 33.
Tan, S. and Belanger, D., J. of Phys. Chem., vol. 109, p. 23480.
Singh, S., Solanki, P.R., Pandey, M.K., and Malhotra, B.D., Sen. Actuators, vol. 115, p. 534.
Ball, I.J., Huang, S.-C., Wolf, R.A., Shimano, J.Y., and Kaner, R.B., J. Membrane Science, 2000, vol. 174, p. 161.
Somani, P., Mandale, A.B., and Radhakrishnan, S., Acta Materialia, 2000, vol. 48, p. 2859.
Shimizu, T., Naruhashi, T., Momma, T., and Osaka, T., J. Electrochem., 2002, vol. 70, no. 12, p. 991.
Sung, J.-Y. and Huang, H.-J., Anal. Chim. Acta, 1991, vol. 246, no. 2, p. 275.
Alpatova, N.M., Andreev, V.N., Danilov, A.I., Molodkina, E.B., Polukarov, Yu.M., Berezina, N.P., Timofeev, S.V., Bobrova, L.P., and Belova, N.N., Elektrokhimiya, 2002, vol. 38, p. 1020 [Russ. J. Elektrochem. (Engl. Transl.), vol. 38, p. 913].
Gnusin, N.P., Karpenko, L.V., Demina, O.A., and Berezina, N.P., Zh. Fiz. Khim., 2001, vol. 75, p. 1697.
Berezina, N.P., Timofeev, S.V., and Kononenko, N.A., J. Membrane Science, 2002, vol. 209, no. 2, p. 509.
Berezina, N.P., Kononenko, N.A., Dvorkina, G.A., and Shel’deshov, N.V., Fiziko-khimicheskie svoistva ionoobmennykh materialov (Physico-Chemical Properties of Ion-Exchange Materials), Krasnodar: KubGU, 1999.
Berezina, N., Gnusin, N., Dyomina, O., and Timofeyev, S., J. Membrane Science, 1994, vol. 86, p. 207.
Karpenko, L.V., Demina, O.A., Dvorkina, G.A., Parshikov, S.B., Larchet, K., Auclair, B., and Berezina, N.P., Elektrokhimiya, 2001, vol. 37, p. 328 [Russ. J. Elektrochem. (Engl. Transl.), vol. 37, p. 287].
Heitner-Wirguin, C., J. Membrane Science, 1996, vol. 120, p. 1.
Ivanov, V.F., Gribkova, O.L., Cheberyako, K.V., Nekrasov, A.A., Tverskoi, V.A., and Vannikov, A.V., Elektrokhimiya, 2004, vol. 40, p. 339 [Russ. J. Elektrochem. (Engl. Transl.), vol. 40, p. 299].
Robinson, R. and Stoks, R., Rastvory elektrolitov (Electrolyte Solutions), Moscow: Iz-vo inostr. lit, 1963.
Kononenko, N.A., Berezina, N.P., and Loza, N.V., Colloids and Surfaces: Physicochem. Eng. Aspects, 2004, vol. 239, p. 59.
Rollet, A.-L., Étude des properiétés physico-chimiques d’ions dans un milieu poreux chargé exemple du Nafion: Thése De doctorat de l’Université Pierre et Marie Curie (Paris VI), Paris: France, 1999.
Berezina, N.P., Timofeev, S.V., Rollet, A.-L., Fedorovich, N.V., and Dyuran-Vidal’, S., Elektrokhimiya, 2002, vol. 38, p. 1009 [Russ. J. Elektrochem. (Engl. Transl.), vol. 38, p. 903].
Gnusin, N.P., Berezina, N.P., Kononenko, N.A., and Dyomina, O.A., J. of Membrane Science, 2004, vol. 243, p. 301.
Belinskaya, F.A., Ionnyi obmen i ionometriya (Ion Exchange and Ionometry), Saint Petersburg: Izd-vo SPbgu, 2000.
Samsonov, G.V., Trostyanskaya, E.B., and El’kin, G.E., Ionnyi obmen. Sorbtsiya organicheskikh veshchestv (Ion Exchange: Sorption of Organic Substances), Leningrad: Nauka, 1969.
Marinskii, A.Ya., Ion Exchange. Theory and Application, Nachod, F., Ed., New York: n.p., 1949.
Berezina, N.P., Kubaisi, A.A., Alpatova, N.M., Andreev, V.N., and Griga, E.I., Elektrokhimiya, 2004, vol. 40, p. 325 [Russ. J. Elektrochem. (Engl. Transl.), vol. 40, p. 286].
Berezina, N.P., Kubaisy, A.A.-R., Timofeev, S.V., and Karpenko, L.V., J. Solid State Electrochem., 2007, vol. 11, no. 3, p. 378.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A.-R. Sycheva, I.V. Falina, N.P. Berezina, 2009, published in Elektrokhimiya, 2009, Vol. 45, No. 1, pp. 114–121.
Rights and permissions
About this article
Cite this article
Sycheva, A.A.R., Falina, I.V. & Berezina, N.P. Sorption and conducting properties of perfluorinated MF-4SC membranes in aqueous solutions containing phenylammonium ions. Russ J Electrochem 45, 108–115 (2009). https://doi.org/10.1134/S1023193509010157
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193509010157