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Conductivity of LiBOB in various ternary solvent blends and the electrochemical performance of LiBOB-PC/EMC/DMC used in Li/MCMB and LiFePO4/Li cells

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Abstract

The solid-state reaction was employed to obtain LiBOB in vacuum dryer at 100°C, with the dryer of P2O5. The resulting LiBOB was employed in various ternary solvent blends to get the k, and its change with salt, solvent composition and temperature. 0.7 M LiBOB-PC/EMC/DMC (1: 1: 1, v: v: v) and 0.5 M LiBOB-EC/EMC/DMC (1: 1: 1, v: v: v) were observed to have better k at wide θ range, and the former was chosen to assemble Li/MCMB and LiFePO4/Li cells. The results indicated that it can stabilize the MCMB anodes, and exhibit good stability in LiFePO4/Li cell.

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References

  1. Hammami, A., Raymond, N., and Armand, M., Nature (London), 2003, vol. 424, p. 635.

    Article  CAS  Google Scholar 

  2. Markusson, H. and Johansson, P., Electrochem. Solid-State Lett., 2005, vol. 8, p. A215.

    Article  CAS  Google Scholar 

  3. Chen, Z., Lu, W.Q., Liu, J., and Amine, K., Electrochim. Acta, 2006, vol. 51, p. 3322.

    Article  CAS  Google Scholar 

  4. Zhang, G.V., Xu, K., Jow, T.R., and Ross, P.N. Jr., Electrochem. Solid-State Lett., 2004, vol. 7, p. A224.

    Article  CAS  Google Scholar 

  5. Xu, K., Zhang, S.S., and Jow, R., J. Power Sources, 2005, vol. 143, p. 197.

    Article  CAS  Google Scholar 

  6. Lischka, U., Wietelmann, U., and Wegner, M., German Pat. DE 19829030 C1, 1999.

  7. Xu, W., and Angell, C.-A., Electrochem. Solid-State Lett., 2001, vol. 4, p. E1.

    Article  CAS  Google Scholar 

  8. Yu, B.T., Qiu, W.H., Li, F.S., and Xu, G.X., Electrochem. Solid-State Lett., 2006, vol. 9, p. A1.

    Article  CAS  Google Scholar 

  9. Larsson, W., Panitz, J.C., and Cedergren, A., Talanta, 2006, vol. 69, p. 276.

    Article  CAS  Google Scholar 

  10. Zhang, S.S., Xu, K., and Jow, T.R., J. Power Sources, 2006, vol. 159, p. 702.

    Article  CAS  Google Scholar 

  11. Ding, M.S., Xu, K., and Jow, T.R., J. Electrochem. Soc., 2002, vol. 149, p. A1489.

    Article  CAS  Google Scholar 

  12. Ding, M.S., J. Electrochem. Soc., 2004, vol. 151, p. A40.

    Article  CAS  Google Scholar 

  13. Ding, M.S., Xu, K., and Jow, T.-R., J. Electrochem. Soc., 2005, vol. 152, p. A132.

    Article  CAS  Google Scholar 

  14. Rodriguez, A., Canosa, J., Dominguez, A., and Tojo, J., J. Chem. Eng. Date, 2003, vol. 48, p. 146.

    Article  CAS  Google Scholar 

  15. Zhang, S.S., Ding, M.S., Xu, K., and Alle, J. Electrochem. Solid-State Lett., 2001, vol. 4, p. A206.

    Article  CAS  Google Scholar 

  16. Blomgren, G.E., J. Power Sources, 2003, vol. 119, p. 32.

    Article  CAS  Google Scholar 

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Correspondence to S. Y. Li.

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Published in Russian in Elektrokhimiya, 2008, Vol. 44, No. 10, pp. 1231–1236.

The text was submitted by the authors in English.

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Li, S.Y., Ma, P.H., Song, S.T. et al. Conductivity of LiBOB in various ternary solvent blends and the electrochemical performance of LiBOB-PC/EMC/DMC used in Li/MCMB and LiFePO4/Li cells. Russ J Electrochem 44, 1144–1148 (2008). https://doi.org/10.1134/S1023193508100091

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  • DOI: https://doi.org/10.1134/S1023193508100091

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