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Study of anionic conductors R1 − y Sr y F3 − y (R = Ce, Pr, Gd) and M1 − x Y x O2 − x/2 (M = Zr, Hf) using four-electrode method

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Abstract

The anionic conductivity parameters are determined for R1 − y Sr y F3 − y (R = Ce, Pr, Gd), Zr0.88Y0.12O1.94 single crystals and Zr0.88Y0.12O1.94|M0.88Y0.12O1.94 (M = Zr, Hf) bicrystals using an ac (5 Hz to 100 kHz) four-electrode method. The obtained conductometric data are compared with the results of studying these crystals using a two-electrode method. It is shown that physical parameters of R1 − y Sr y F3 − y fluoride crystals with the tysonite (LaF3) structure are stable at heating in air up to the temperatures of 200–300°C, which is important for their practical application.

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References

  1. Orlyukas, A.S., Kezhenes, A.P., Mikuchenis, V.F., and Vaitkus, R.A., Elektrokhimiya, 1987, vol. 23, p. 98.

    Google Scholar 

  2. Kokabi, H.R., Provost, J., and Desgardin, G., Rev. Sci. Instrum., 1993, vol. 64, no. 6, p. 547.

    Article  Google Scholar 

  3. Fafilek, G., Breiter, W., J. Electroanal. Chem., 1997, vol. 430, nos. 1–2, p. 269.

    Article  CAS  Google Scholar 

  4. Sorokin, N.I., Fominykh, M.V., Krivandina, E.A., Zhmurova, Z.I., and Sobolev, B.P., Kristallografiya, 1996, vol. 41, no. 2, p. 310 [Crystallogr. Rep. (Engl. Transl.), vol. 41, no. 2, p. 292].

    CAS  Google Scholar 

  5. Sorokin, N.I., Elektrokhimiya, 2000, vol. 36, p. 357 [Russ. J. Elektrochem. (Engl. Transl.), vol. 36, p. 319].

    Google Scholar 

  6. Reau, J.M. and Grannec, J., in Inorganic Solid Fluorides: Chemistry and Physics, Hagenmuller, P., Ed., London: Academic Press, 1985, p. 423.

    Google Scholar 

  7. Kudo, T. and Fueki, K., Solid State Ionics. Kodansha. VCH Verlags AG, 1990.

  8. Sobolev, B.P., Aleksandrov, V.B., Fedorov, P.P., Seiranyan, K.B., and Tkachenko, N.L., Kristallografiya, 1976, vol. 21, no. 1, p. 96.

    CAS  Google Scholar 

  9. Tzalenchuk, A.Ya., Regel, V.R., and Stepantsov, E.A., Mater. Sci. Forum, 1990, vol. 42, no. 8, p. 393.

    Google Scholar 

  10. Aleksandrov, V.I., Osiko, V.V., Prokhorov, A.M., and Tatarintsev, V.M., Usp. Khim., 1978, vol. 47, p. 385.

    CAS  Google Scholar 

  11. Radaev, S.F., Krivandina, E.A., Muradyan, L.A., Maksimov, B.A., Bydanov, N.N., Sarin, V.A., Sobolev, B.P., and Simonov, V.I., Kristallografiya, 1991, vol. 36, no. 2, p. 369.

    CAS  Google Scholar 

  12. Tien, S., Charnaya, E.V., and Sherman, A.V., Fiz. Tverd. Tela, 2004, vol. 46, no. 9, p. 1578.

    Google Scholar 

  13. Denecke, M.A., Gunsser, W., Privalov, A.V., and Murin, I.V., Solid State Ionics, 1992, vol. 52, p. 327.

    Article  CAS  Google Scholar 

  14. Izosimova, M.G., Livshits, A.I., Buznik, V.M., Fedorov, P.P., Krivandina, E.A., and Sobolev, B.P., Fiz. Tverd. Tela, 1986, vol. 28, no. 9, p. 2644.

    CAS  Google Scholar 

  15. Sorokin, N.I., Krivandina, E.A., Zhmurova, Z.I., and Sobolev, B.P., in Proc. 4th Inter. Conf. “Single Crystal Growth and Heat & Mass Transfer”, Ginkin, V.P., Ed., SSC RF IPPE, Obninsk, 2001, vol. 1, p. 167.

    Google Scholar 

  16. Takahashi, T., Iwahara, H., and Ishikawa, T., J. Electrochem. Soc., 1977, vol. 124, no. 2, p. 280.

    Article  CAS  Google Scholar 

  17. Murin, I.V., Glumov, O.V., and Sobolev, B.P., Vestn. Leningr. Univ., 1980, no. 10, p. 84.

  18. Murin, I.V., Glumov, O.V., and Amelin, Yu.V., Zh. Prikl. Khim., 1980, vol. 53, no. 7, p. 1474.

    CAS  Google Scholar 

  19. Roos, A., van de Pol, F.C.M., Keim, R., and Schoonman, J., Solid State Ionics, 1984, vol. 13, p. 191.

    Article  CAS  Google Scholar 

  20. Kröger, F.A., The Chemistry of Imperfect Crystals, Amsterdam: North-Holland, 1964.

    Google Scholar 

  21. Sobolev, B.P., Aleksandrov, V.B., Fedorov, P.P., Seiranyan, K.B., and Tkachenko, N.L., Kristallografiya, 1976, vol. 21, no. 21, p. 96.

    CAS  Google Scholar 

  22. Badwal, S.P.S., Solid State Ionics, 1992, vol. 52, p. 23.

    Article  CAS  Google Scholar 

  23. Filal, M., Petot, C., Mokchah, M., Chateau, C., and Carpentier, J.L., Solid State Ionics, 1995, vol. 80, p. 27.

    Article  CAS  Google Scholar 

  24. Chebotin, V.N. and Perfil’ev, M.V., Elektrokhimiya tverdykh elektrolitov (Electrochemistry of Solid Electrolytes), Moscow: Khimiya, 1978.

    Google Scholar 

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia

    N. I. Sorokin & B. P. Sobolev

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  1. N. I. Sorokin
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  2. B. P. Sobolev
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Correspondence to N. I. Sorokin.

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Original Russian Text © N.I. Sorokin, B.P. Sobolev, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 9, pp. 1111–1115.

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Sorokin, N.I., Sobolev, B.P. Study of anionic conductors R1 − y Sr y F3 − y (R = Ce, Pr, Gd) and M1 − x Y x O2 − x/2 (M = Zr, Hf) using four-electrode method. Russ J Electrochem 44, 1031–1035 (2008). https://doi.org/10.1134/S1023193508090073

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  • DOI: https://doi.org/10.1134/S1023193508090073

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