Abstract
Peculiarities of ohmic conductivity of 1–1 binary electrolyte solutions at finite frequencies are considered. Reference to this well-known problem is associated with the lack of information in the literature about the frequency dependence of effective masses of ions involved in the dynamics of a conducting liquid. A comparison of the Drude linear dynamics and the same problem in the Stokes approximation confirms the invalidity of such simplification and the necessity of making corrections for the frequency dispersion of effective masses of electrolyte ions when considering different dynamic problems.
This is a preview of subscription content, log in via an institution to check access.
References
Hansen, J.-P. and McDonald, I.R., Theory of Simple Liquids, New York: Elsevier, 2006.
Rotinyan, A.L., Tikhonov, K.I., and Shoshina, I.A., Teoreticheskaya Elektrokhimiya (Theoretical Electrochemistry), Leningrad: Khimiya, 1981.
March, N. and Tosi, M., Dvizhenie atomov zhidkosti (Motion of Liquid Atoms), Moscow: Metallurgiya, 1980.
Grafov, B.M. and Ukshe, E.A., Elektrokhimicheskie tsepi peremennogo toka (Electrochemical AC Circuits), Moscow: Nauka, 1973.
Ansel’m, A.I., Vvedenie v teoriyu poluprovodnikov (Introduction to Semiconductor Theory), Moscow: Nauka, 1978.
Trullas, J., Giro, A., and Padro, J.A., J. Chem. Phys., 1989, vol. 91, p. 539; 1990, vol. 93, p. 5177.
Lamb, H., Hydrodynamics, New York: Cambridge Univ. Press, 1993.
Landau, L.D. and Lifshitz, E.M., Gidrodinamika (Hydrodynamics), Moscow: Nauka, 1986.
Chikina, I., Shikin, V., and Varlamov, A., Phys. Rev. B, 2007, vol. 75, p. 184518.
Dahm, A. and Sanders, T., J. Low Temp. Phys., 1970, vol. 2, p. 199.
Ott-Rowland, M.L., Kotsubo, V., Theobald, J., and Williams, G.H., Phys. Rev. Lett., 1982, vol. 49, p. 1708.
Mellor, C., Muirhead, C., Travers, J., and Vinen, W., J. Phys. C: Solid State Phys., 1988, vol. 21, p. 325.
Mellor, C., Muirhead, C., Travers, J., and Vinen, W., Surf. Sci., 1988, vol. 196, p. 33.
Davis, H., Rice, S., and Meyer, L., J. Chem. Phys., 1962, vol. 37, p. 2470.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.B. Shikin, I.S. Smirnova, S.S. Nazin, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 8, pp. 1045–1049.
Rights and permissions
About this article
Cite this article
Shikin, V.B., Smirnova, I.S. & Nazin, S.S. On conductivity of electrolytes at finite frequencies. Russ J Electrochem 44, 972–976 (2008). https://doi.org/10.1134/S1023193508080156
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193508080156