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Palladium deposition features on poly-o-phenylenediamine film

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Abstract

Palladium electrodeposition on poly-o-phenylenediamine (PPD) redox polymer was studied. Palladium electrodeposition was shown to be initiated at the ITO/polymer interface with further proliferation into the polymeric matrix and passing by mediator mechanism. PPD exposure to PdCl2 solution was shown to result in the accumulation of palladium ions in the polymer matrix with partial substitution of counter ions linked to nitrogen atom. Upon rinsing, the film retains some palladium ions, which can be reduced to metal.

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Authors and Affiliations

  1. A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    E. Yu. Pisarevskaya & N. M. Alpatova

Authors
  1. E. Yu. Pisarevskaya
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  2. N. M. Alpatova
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Correspondence to E. Yu. Pisarevskaya.

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Published in Russian in Elektrokhimiya, 2008, Vol. 44, No. 8, pp. 1035–1039.

The text was submitted by the authors in English.

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Pisarevskaya, E.Y., Alpatova, N.M. Palladium deposition features on poly-o-phenylenediamine film. Russ J Electrochem 44, 962–966 (2008). https://doi.org/10.1134/S1023193508080132

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  • DOI: https://doi.org/10.1134/S1023193508080132

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