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Specific features of the behavior of an electrochemical system in the case of the Hopf instability for a spherical electrode

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Abstract

Model approximations are developed that allow establishing a quantitative relationship between the geometrical parameters of a spherical electrode, the faradaic impedance, and instabilities of the electrochemical system for an electrode reaction under potentiostatic conditions for the adsorption of species preceding their discharge. It is shown that the control parameter ωH in the Hopf bifurcation point depends on the electrode size. The effect of the Nernst diffusion layer is observed at low frequencies in the range of negative faradaic impedance values.

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Authors and Affiliations

  1. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32-34, Kiev, 252142, Ukraine

    V. V. Pototskaya, A. A. Omelchuk & S. V. Volkov

  2. Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    O. I. Gichan

Authors
  1. V. V. Pototskaya
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  2. O. I. Gichan
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  3. A. A. Omelchuk
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  4. S. V. Volkov
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Corresponding authors

Correspondence to V. V. Pototskaya or A. A. Omelchuk.

Additional information

Original Russian Text © V.V. Pototskaya, O. I. Gichan, A.A. Omelchuk, S.V. Volkov, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 5, pp. 641–648.

The paper was prepared for special issue devoted to V.G. Levich 90th anniversary.

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Pototskaya, V.V., Gichan, O.I., Omelchuk, A.A. et al. Specific features of the behavior of an electrochemical system in the case of the Hopf instability for a spherical electrode. Russ J Electrochem 44, 594–601 (2008). https://doi.org/10.1134/S1023193508050145

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  • DOI: https://doi.org/10.1134/S1023193508050145

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