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Dynamics of lithium electrode passivation in aprotic organic electrolytes, studied by electrochemical noise method

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Abstract

Lithium electrode passivation is studied in different organic electrolytes, namely, 1 M LiClO4 in 1,3-dioxolane, 1 M LiN(CF3SO2)2 in 1,3-dioxolane, 1 M LiPF6 in an ethylene carbonate-diethyl carbonate mixture, 1 M LiPF6 in an ethylene carbonate-dimethyl carbonate mixture, using the electrochemical noise method. The dynamics of passive film formation on the lithium surface in the mentioned electrolytes that differ in their corrosivity towards lithium is followed.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    L. S. Kanevskii & B. M. Grafov

Authors
  1. L. S. Kanevskii
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  2. B. M. Grafov
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Correspondence to L. S. Kanevskii.

Additional information

Original Russian Text © L.S. Kanevskii, B.M. Grafov, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 5, pp. 615–619.

The paper is published based on the materials presented at the International Conference “Fundamental Problems of Energy Conversion in Lithium Electrochemical Systems”, Ufa, 2006.

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Kanevskii, L.S., Grafov, B.M. Dynamics of lithium electrode passivation in aprotic organic electrolytes, studied by electrochemical noise method. Russ J Electrochem 44, 570–574 (2008). https://doi.org/10.1134/S1023193508050108

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  • DOI: https://doi.org/10.1134/S1023193508050108

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