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Modeling of specific adsorption of ions at electrodes during the passing from a mixed solution of constant ionic strength to a binary solution

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Abstract

Electrocapillary curves in the mc NaNO3 + (1 − m)c NaF mixed solutions are calculated in terms of the Alekseev-Popov-Kolotyrkin model. The analysis of limiting case m = 1 shows that in a NaNO3 binary solution the model predicts quadratic dependence of the NO −3 anion adsorption energy on the potential, which contradicts to experimental data. A modification of the model is suggested, which allowed removing this contradiction.

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Authors and Affiliations

  1. Moscow State University, Vorob’evy Gory, Moscow, 119899, Russia

    B. B. Damaskin

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  1. B. B. Damaskin
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Correspondence to B. B. Damaskin.

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Original Russian Text © B.B. Damaskin, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 3, pp. 373–378.

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Damaskin, B.B. Modeling of specific adsorption of ions at electrodes during the passing from a mixed solution of constant ionic strength to a binary solution. Russ J Electrochem 44, 347–352 (2008). https://doi.org/10.1134/S1023193508030142

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  • DOI: https://doi.org/10.1134/S1023193508030142

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