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Structural features of the electrode/solution interface at the reduction of Cr3+(aq) cations on liquid mercury and solid indium electrodes in acidic media

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Abstract

Characteristics of electroreduction of Cr3+ and Cr2+ ions on the dropping mercury (literature data) and indium cathodes are analyzed as a function of pH of the medium. A hypothesis that polymeric hydroxocompounds of chromium, which are present in different aggregate states, represent the main or partial reactants in the \( Cr\left( {III} \right)\xrightarrow{{ + e}}Cr\left( {II} \right)\xrightarrow{{ + 2e}}Cr \) stages is additionally substantiated.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Vorob’evy Gory, Moscow, 119992, Russia

    V. N. Korshunov, V. A. Safonov & L. N. Vykhodtseva

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  1. V. N. Korshunov
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  2. V. A. Safonov
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  3. L. N. Vykhodtseva
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Correspondence to V. A. Safonov.

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Original Russian Text © V.N. Korshunov, V.A. Safonov, L.N. Vykhodtseva, 2008, published in Elektrokhimiya, 2008, Vol. 44, No. 3, pp. 275–285.

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Korshunov, V.N., Safonov, V.A. & Vykhodtseva, L.N. Structural features of the electrode/solution interface at the reduction of Cr3+(aq) cations on liquid mercury and solid indium electrodes in acidic media. Russ J Electrochem 44, 255–264 (2008). https://doi.org/10.1134/S1023193508030014

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  • DOI: https://doi.org/10.1134/S1023193508030014

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