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Electrogeneration of peroxodicarbonate anion: Synthesis of tetraalkylammonium silylcarboxylate

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Abstract

Oxygen electroreduction in the presence of CO2 in acetonitrile solutions of tetraalkylammonium salts is a means to produce tetraalkylammonium peroxodicarboxylates. The latter react with triorganosilanes R3SiH to yield tetraalkylammonium salts of triorganylsilylcarboxylic acids. Diorganylsilanes under the same conditions produce cyclic siloxanes exclusively.

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Authors and Affiliations

  1. Laboratoire d’Electrochimie Organique, Université de Rennes 1, Rennes, 35042, France

    K. N. Singh, S. Neuhold, C. Grogger & V. V. Jouikov

Authors
  1. K. N. Singh
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  2. S. Neuhold
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  3. C. Grogger
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  4. V. V. Jouikov
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Correspondence to V. V. Jouikov.

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Original Russian Text © K.N. Singh, S.Neuhold, C.Grogger, V.V. Jouikov, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 10, pp. 1234–1238.

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Singh, K.N., Neuhold, S., Grogger, C. et al. Electrogeneration of peroxodicarbonate anion: Synthesis of tetraalkylammonium silylcarboxylate. Russ J Electrochem 43, 1170–1174 (2007). https://doi.org/10.1134/S1023193507100102

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  • DOI: https://doi.org/10.1134/S1023193507100102

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