Abstract
An alternative approach to synthesis of electrophilic terminal phosphinidene complexes of tungsten pentacarbonyl with various substituents at the phosphorus atom has been developed. The approach is based on the reaction of the electrochemically generated tungsten pentacarbonyl ion with trivalent phosphorus acyl chlorides. Electrochemical reduction of ethyldichlorophosphines in the presence of α-diimines is a one-step process that forms 1,3,2-diazaphospholenes containing an exocyclic P-C bond.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Mathey, F., in Multiple Bonds and Low Coordination in Phosphorus Chemistry, Regitz, M. and Scherer, O., Eds., Stuttgart: G. Thiene Verlag, 1990.
Henderson, W., Eppstein, M., and Seichter, F.S., J. Am. Chem. Soc., 1963, vol. 85, p. 2462.
Schmidt, U. and Osterroht, Ch., Angew. Chem., 1965, vol. 77, p. 455.
Jaud, J., Couret, C., and Escudie, J., J. Organometal. Chem., 1983, vol. 249, p. C25; Cowley, A.H., Acc. Chem. Res., 1984, vol. 17, p. 384.
Joshifuji, M., Sato, T., and Inamoto, N., Chem. Lett., 1988, p. 1735.
Li, X., Weissman, S.I., Lin, T.S., Gaspar, P.P., Cowley, A.H., and Smirnov, A.I., J. Am. Chem. Soc., 1994, vol. 116, p. 7899.
Cowley, A.H., Acc. Chem. Res., 1997, vol. 30, p. 445.
Bonano, J.B., Wolczanski, P.T., and Lobkovsky, E.B., J. Am. Chem. Soc., 1994, vol. 116, p. 11159.
Mathey, F., Huy, N.H.T.H., and Marinetti, A., Helv. Chim. Acta, 2001, vol. 84, p. 2938.
Marinetti, A., Mathey, F., Fischer, J., and Mitschler, A., J. Am. Chem. Soc., 1982, vol. 104, p. 4484; Marinetti A., Mathey, F., Fischer, J., and Mitschler, A., J. Chem. Soc., Chem. Commun., 1987, p. 667.
Budnikova, Yu.G., Gryaznova, T.V., Yagfarov, A.R., and Sinyashin, O.G., Izv. Akad. Nauk, Ser. Khim., 2005, p. 1356.
Budnikova, Yu.G., Petrukhina, O.E., Titova, Z.S., and Kargin, Yu.M., Zh. Obshch. Khim., 1996, vol. 66, p. 1239.
Flynn, K.M., Olmstead, M.M., and Power, P.P., J. Am. Chem. Soc., 1983, vol. 105, p. 2085.
Mathey, F. and Marinetti, A., Organometallics, 1984, vol. 3, p. 456.
Alcaraz, J.-M., Svara, J., and Mathey, F., New J. Chem., 1986, vol. 10, p. 321.
Streubel, R., Ostwski, A., Wilkens, H., Ruthe, F., Jeske, J., and Jones, P.G., Angew. Chem., Int. Ed., 1997, vol. 36, p. 378; Tran Huy, N.H., Ricard, L., and Mathey, F., Heteroatom. Chem., 1998, vol. 9, p. 597.
Eis, M.J., Nijbacker, T., Kanter, F.J.J., Wolf, W.H., Lammertsma, K., and Bickelhaupt, F., J. Amer. Chem. Soc., 2000, vol. 122, p. 3033; Lammertsma, K., Hung, J.-T., Chang, P., and Gray, G.M., J. Org. Chem., 1992, vol. 57, p. 6557.
Eis, M.J., Nijbacker, T., Kanter, F.J.J., Wolf, W.H., Lammertsma, K., Bickelhaupt, F., Lutz, M., and Spek, A.L., Tetrahedron, 2000, vol. 56, p. 129.
Dessy, R.E., Chivers, T., and Kitching, W., J. Am. Chem. Soc., 1966, vol. 88, p. 467.
Gryaznova, T.V., Kibardin, A.M., and Pudovik, A.N., Izv. Akad. Nauk. Ser. Khim., 1987, p. 1676; Gryaznova, T.V., Kibardin, A.M., and Pudovik, A.N., Izv. Akad. Nauk, Ser. Khim., 1986, p. 960.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.V. Gryaznova, Yu.G. Budnikova, O.G. Sinyashin, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 10, pp. 1214–1219.
Rights and permissions
About this article
Cite this article
Gryaznova, T.V., Budnikova, Y.G. & Sinyashin, O.G. Electrochemical approaches to generation of phosphinidene complexes of tungsten pentacarbonyl. Russ J Electrochem 43, 1151–1155 (2007). https://doi.org/10.1134/S1023193507100072
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1023193507100072