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Dynamic criterion of the complex formation and the structure of molten halides: To the fortieth anniversary of the autocomplex model for the structure of melts

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Abstract

The results of my latest research into molten halides of alkali and alkaline-earth metals by a method of Raman spectroscopy are reviewed. A dynamic criterion for the formation of complexes in melts is considered. The results that testify to the existence of instantaneous and short-lived autocomplexes in these liquids are analyzed in the light of an autocomplex model for the structure of melts.

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Authors and Affiliations

  1. Joint Department of Electrochemical Energy Systems, national Academy of Sciences of Ukraine, Vernadsky Ave. 38-A, Kiev, 03142, Ukraine

    S. A. Kirillov

  2. Institute of Sorption and Endoecology, National Academy of Sciences of Ukraine, ul. generala Naumova 13, Kiev, 03164, Ukraine

    S. A. Kirillov

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  1. S. A. Kirillov
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Correspondence to S. A. Kirillov.

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Original Russian Text © S.A. Kirillov, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 8, pp. 949–956.

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Kirillov, S.A. Dynamic criterion of the complex formation and the structure of molten halides: To the fortieth anniversary of the autocomplex model for the structure of melts. Russ J Electrochem 43, 901–908 (2007). https://doi.org/10.1134/S1023193507080083

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  • DOI: https://doi.org/10.1134/S1023193507080083

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