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Redox-switchable binding of the Mg2+ ions by 21,31-diphenyl-12,42-dioxo-7,10,13-trioxa-1,4(3,1)-diquinoxaline-2(2,3),3(3,2)-diindolysine-cyclopentadecaphane

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Abstract

The binding of the Li+, Na+, K+, Mg2+, and Co2+ ions by 21,31-diphenyl-12,42-dioxo-7,10,13-trioxa-1,4(3,1)-diquinoxaline-2(2,3),3(3,2)-diindolysine-cyclopentadecaphane containing two indolysine fragments, two quinoxaline fragments, and 3,6,9-trioxyundecane spacer in the acetonitrile/0.1 M Bu4NBF4 environment is studied by the method of cyclic voltammetry. It is demonstrated that the Li+, Na+, K+, and Co2+ ions are not bound by this macrocycle, whereas selective redox-switchable binding is observed for the Mg2+ ions. The macrocycle binds the Mg2+ ions way more efficiently as compared with its radical cation and dication. The indolysinequinoxaline fragments play the determining role in the binding.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. akademika Arbuzova 8, Kazan, Tatarstan, 420088, Russia

    V. V. Yanilkin, N. V. Nastapova, V. A. Mamedov, A. A. Kalinin & V. P. Gubskaya

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  1. V. V. Yanilkin
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  2. N. V. Nastapova
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  3. V. A. Mamedov
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  4. A. A. Kalinin
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  5. V. P. Gubskaya
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Correspondence to V. V. Yanilkin.

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Original Russian Text © V.V. Yanilkin, N.V. Nastapova, V.A. Mamedov, A.A. Kalinin, V.P. Gubskaya, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 7, pp. 808–814.

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Yanilkin, V.V., Nastapova, N.V., Mamedov, V.A. et al. Redox-switchable binding of the Mg2+ ions by 21,31-diphenyl-12,42-dioxo-7,10,13-trioxa-1,4(3,1)-diquinoxaline-2(2,3),3(3,2)-diindolysine-cyclopentadecaphane. Russ J Electrochem 43, 770–775 (2007). https://doi.org/10.1134/S1023193507070051

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  • DOI: https://doi.org/10.1134/S1023193507070051

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