Skip to main content
SpringerLink
Log in

Employing sulfide-conductive solid electrolytes for the production of semiconducting sulfides with controlled composition and properties

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Nonstoichiometry of sulfides of cadmium and lead is studied by the method of coulometric titration in electrochemical cells with sulfide-conductive solid electrolytes on the basis of MLn2S4. The range of the homogeneity region is estimated at temperatures 300 to 400°C. A feasible model for the formation of defects in nonstoichiometric sulfides of cadmium and lead is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kalinina, L.A. and Shirokova, G.I., Perspektiva poiska sul’fidprovodyashchikh tverdykh elektrolitov (Perspectives for Searching Sulfide-Conducting Solid Electrolytes, Available from ONIITEKhKhIM, Cherkassy, no. 173-XII-88.

  2. Kalinina, L.A., Shirokova, G.I., Murin, I.V., Ushakova, Yu.N., and Fominykh, E.G., Zh. Prikl. Khim., 2000, vol. 73, p. 1324.

    CAS  Google Scholar 

  3. Ushakova, Yu.N., Kalinina, L.A., Fominykh, E.G., Yurlov, I.S., and Murin, I.V., Elektrokhimiya, 2005, vol. 41, p. 707.

    Google Scholar 

  4. Kalinina, L.A., Shirokova, G.I., Lyalina, M.Yu., and Murin, I.V., Sb. Nauch. Tr. UTs RAN, 1991, p. 18.

  5. Fominykh, E.G., Kalinina, L.A., Murin, I.V., and Shirokova, G.I., Vestn. SPbGU: Ser. 4, 1997, no. 4, p. 71.

  6. Abrikosov, N.Kh., and Shelimova, L.E., Poluprovodnikovye materialy na osnove soedinenii A IV B VI (Semiconducting Materials on the Basis of Compounds AIVBVI), Moscow: Nauka, 1975.

    Google Scholar 

  7. Soedineniya peremennogo sostava (Compounds of Variable Compositions), Ormont, B.F., Ed., Moscow: Khimiya, 1969.

    Google Scholar 

  8. Tret’yakov, Yu.D., Khimiya nestekhiometricheskikh okislov (The Chemistry of Nonstoichiometric Oxides), Moscow: Mosk. Gos. Univ., 1974.

    Google Scholar 

  9. Tret’yakov, Yu.D., Tverdofaznye reaktsii (The Solid-Phase Reactions), Moscow: Khimiya, 1978.

    Google Scholar 

  10. Kroeger, F.A., The Chemistry of Imperfect Crystals, Amsterdam: North-Holland, 1964.

    Google Scholar 

  11. Kalinina, L.A., Fominykh, E.G., Tsirenova, L.S., Ushakova, Yu.N., Shirokova, G.I., and Murin, I.V., Zh. Prikl. Khim., 2000, vol. 73, p. 957.

    CAS  Google Scholar 

  12. Leushina, A.P., Extended Abstract, Cand. Sci. (Chem.) Dissertation, Kiev: IONKh, 1977.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Vyatka State University, ul. Moskovskaya 36, Kirov, 610000, Russia

    E. G. Fominykh, L. A. Kalinina, Yu. N. Ushakova, G. I. Shirokova, T. I. Rychkova & B. A. Ananchenko

Authors
  1. E. G. Fominykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Kalinina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. N. Ushakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. I. Shirokova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. I. Rychkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. A. Ananchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. N. Ushakova.

Additional information

Original Russian Text © E.G. Fominykh, L.A. Kalinina, Yu.N. Ushakova, G.I. Shirokova, T.I. Rychkova, B.A. Ananchenko, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 5, pp. 571–577.

Based on the paper delivered at the 8th Meeting “Fundamental Problems of Solid-State Ionics”, Chernogolovka (Russia), 2006.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fominykh, E.G., Kalinina, L.A., Ushakova, Y.N. et al. Employing sulfide-conductive solid electrolytes for the production of semiconducting sulfides with controlled composition and properties. Russ J Electrochem 43, 545–551 (2007). https://doi.org/10.1134/S1023193507050072

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193507050072

Key words

Search

Navigation