Skip to main content
SpringerLink
Log in

Lanthanum-strontium cuprate: A promising cathodic material for solid oxide fuel cells

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Samples of lanthanum-strontium cuprate LaSrCuO3.61 are synthesized by a solid-phase method at 1473 K, in air. Electron diffraction patterns reveal low-intensity satellites whose position is described in the reciprocal space by the (3 + 2)-dimensional space group I4/mmm(αα0, α-α0)00mg. Using a five-layer cell LaSrCuO4-δ|YSZ|LaSrCuO4-δ|YSZ|LaCuO4-δ prepared by isostatic hot pressing, the ionic component of conductivity of LaSrCuO4-δ is determined (σ1179 K = 3.8 × 10−3 S cm−1), which is commensurate with other mixed conductors based on complex oxides of cobalt and iron.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mihn, N.Q., J. Am. Ceram. Soc., 1993, vol. 76, p. 563.

    Article  ADS  Google Scholar 

  2. Simner, S.P., Bonnett, J.F., Canfield, N.L., Meinhardt, K.D., Shelton, J.P., Sprenkle, V.L., and Stevenson, J.W., J. Power Sources, 2003, vol. 113, p. 1.

    Article  CAS  Google Scholar 

  3. Signal, S.C., MRS Bull., 2000 (March), p. 16.

  4. Yu. H.C. and Fung, K.-Z., J. Power Sources, vol. 132, p. 162.

  5. Van Roosmalen, J.A.M. and Cordfunke, E.H.P., Solid State Ionics, 1992, vol. 52, p. 303.

    Article  Google Scholar 

  6. Takeda, Y., Sakaki, Y., Ichikawa, I., Imanishi, N., Yamamoto, O., Mori, M., Mori, N., and Abe, T., Solid State Ionics, 1994, vol. 72, p. 257.

    Article  CAS  Google Scholar 

  7. Simner, S.P., Sheldon, J.P., Anderson, M.D., and Stevenson, J.W., Solid State Ionics, 2003, vol. 161, p. 11.

    Article  CAS  Google Scholar 

  8. Goedickemeier, M., Sasaki, K., Gauckler, L.J., and Riess, I., Solid State Ionics, 1996, vol. 86–88, p. 691.

    Article  Google Scholar 

  9. Maguire, E., Gharbage, B., Marques, F.M.B., and Labrincha, J.A., Solid State Ionics, 2000, vol. 127, p. 329.

    Article  CAS  Google Scholar 

  10. Steele, B.C.H., Hori, K.M., and Uchino, S., Solid State Ionics, 2000, vol. 135, p. 445.

    Article  CAS  Google Scholar 

  11. Colomer, M.T., Steele, B.C.H., and Kilner, J.A, Solid State Ionics, 2002, vol. 147, p. 41.

    Article  CAS  Google Scholar 

  12. Savvin, S.N., Mazo, G.N., and Ivanov-Schitz, A.K., Defect Diffus. Forum, Pt. A, 2005, vol. 242–244, p. 27.

    Google Scholar 

  13. Mazo, G.N., Savvin, S.N., Mychka, E.V., Dobrovol’skii, Yu.A., and Leonova, L.S., Elektrokhimiya, 2005, vol. 41, p. 516.

    Google Scholar 

  14. Radaelli, P.G., Hinks, D.G., Mitchell, A.W., Hunter, B.A., Wagner, J.L., Dabrowski, B., Vandervoort, K.G., Viswanathan, H.K., and Jorgensen, J.D., Phys. Rev. B, 1994, vol. 49, p. 4163.

    Article  ADS  CAS  Google Scholar 

  15. Tagaki, H., Cava, R.J., Marezio, M., Battlog, B., Krajewski, J.J., and Peck, W.F. Jr., Phys. Rev. Lett., 1992, vol. 68, p. 3777.

    Article  ADS  Google Scholar 

  16. De Wolff, P.M., Acta Cryst. A, 1974, vol. 30, p. 777.

    Article  Google Scholar 

  17. De Wolff, P.M., Janssen, T., and Janner, A., Acta Cryst. A, 1981, vol. 37, p. 625.

    Article  Google Scholar 

  18. Gillie, L.J., Wright, A.J., Hadermann, J., van Tendeloo, G., and Greaves, C., J. Solid State Chem., 2003, vol. 175, p. 188.

    Article  ADS  CAS  Google Scholar 

  19. Van Doorn, R.H.E. and Burggraaf, A.J., Solid State Ionics, 2000, vol. 128, p. 65.

    Article  Google Scholar 

  20. Bucher, E., Sitte, W., Rom, I., Papst, I., Grogger, W., and Hofer, F., Solid State Ionics, 2002, vol. 152–153, p. 417.

    Article  Google Scholar 

  21. Yoshimura, K., Kubota, H., Tanaka, H., Date, Y., Nakanishi, M., Ohmure, T., Saga, N., Sawamura, T., and Uemura, T., J. Phys. Soc. Jpn., 1993, vol. 62, p. 1114.

    Article  CAS  Google Scholar 

  22. Routbort, J.L., Rothman, S.J., Flandermeyer, B.K., Nowicki, L.J., and Baker, J.E., J. Mater. Res., 1988, vol. 3, p. 116.

    ADS  CAS  Google Scholar 

  23. Opila, E.J., Tuller, H.L., Wuensch, B.J., and Maier, J., J. Am. Ceram. Soc., 1993, vol. 76, p. 2363.

    Article  ADS  CAS  Google Scholar 

  24. Caciuoffo, R., Rinaldi, D., Barucca, G., Mira, J., Rivas, J., Senaris-Rodriguez, M.A., Radaelli, P.G., Fiorani, D., and Goodenough, G.B., Phys. Rev., B, 1999, vol. 59, p. 1068.

    Article  ADS  Google Scholar 

  25. Bukun, N.G., Ukshe, A.E., and Ukshe, E.A., Elektrokhimiya, 1993, vol. 29, p. 110.

    CAS  Google Scholar 

  26. Aoki, M., Chiang, Y.-M., Kosacki, I., Lee, L.J.-R., Tuller, H., and Liu, Y., J. Am. Ceram. Soc., 1996, vol. 79, p. 1169.

    Article  CAS  Google Scholar 

  27. Luo, J., Almond, D.P., and Stevens, R., J. Am. Ceram. Soc., 2000, vol. 83, p. 1703.

    Article  CAS  Google Scholar 

  28. Zipprich, W. and Wiemhoefer H.D., Solid State Ionics, 2000, vol. 135, p. 699.

    Article  CAS  Google Scholar 

  29. Kharton, V.V. and Marques, F.M.B., Curr. Opin. Solid State Mater. Sci., 2002, vol. 6, p. 261.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State University, Vorob’evy Gory 1, Moscow, 119992, Russia

    G. N. Mazo, S. N. Savvin & A. M. Abakumov

  2. University of Antwerp, Groenenborgerlaan 172, Antwerp, B-2020, Belgium

    J. Hadermann

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    Yu. A. Dobrovol’skii & L. S. Leonova

Authors
  1. G. N. Mazo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. N. Savvin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Abakumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Hadermann
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. A. Dobrovol’skii
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. S. Leonova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G. N. Mazo.

Additional information

Original Russian Text © G.N. Mazo, S.N. Savvin, A.M. Abakumov, J. Hadermann, Yu.A. Dobrovol’skii, L.S. Leonova, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 4, pp. 459–465.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mazo, G.N., Savvin, S.N., Abakumov, A.M. et al. Lanthanum-strontium cuprate: A promising cathodic material for solid oxide fuel cells. Russ J Electrochem 43, 436–442 (2007). https://doi.org/10.1134/S1023193507040106

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193507040106

Key words

Search

Navigation