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Effect of composition changes on properties and defect structure of crystalline Sm-doped ZrO2

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Abstract

Polymorphous structure, electrical conductivity, absorption coefficient, refractive index, and mechanical characteristics of crystalline system ZrO2 + x Sm2O3 (x = 4–43 mol %) is investigated. Vickers microhardness is investigated by the well-known quasi-static indentation method. Plastic microhardness and the effective elastic modulus are studied by the depth-sensing indentation technique. Special attention is devoted to the ordered defect fluorite structure, pyrochlore phase Sm2Zr2O7, observed for x = 43 mol %. Potential applications of the investigated system are discussed.

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Authors and Affiliations

  1. Institute of Physics, Slovak Academy of Sciences, 84511, Bratislava, Slovakia

    M. Hartmanová & M. Jergel

  2. Institute for Chemical Technologies and Analytics, Vienna University of Technology, A-1060, Vienna, Austria

    F. Kubel

  3. Masaryk University, 61137, Brno, Czech Republic

    V. Buršková, V. Navrátil, K. Navratil & I. Kosti

  4. General Physics Institute, Russian Academy of Sciences, Moscow, 117942, Russia

    E. E. Lomonova

  5. Comenius University, 84228, Bratislava, Slovakia

    F. Kundracik

  6. Institute of Informatics, Slovak Academy of Sciences, 84507, Bratislava, Slovakia

    I. Kosti

Authors
  1. M. Hartmanová
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  2. F. Kubel
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  3. V. Buršková
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  4. M. Jergel
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  5. V. Navrátil
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  6. E. E. Lomonova
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  7. K. Navratil
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  8. F. Kundracik
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Additional information

Published in Russian in Elektrokhimiya, 2007, Vol. 43, No. 4, pp. 402–411.

The text was submitted by the authors in English.

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Hartmanová, M., Kubel, F., Buršková, V. et al. Effect of composition changes on properties and defect structure of crystalline Sm-doped ZrO2 . Russ J Electrochem 43, 381–389 (2007). https://doi.org/10.1134/S1023193507040040

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  • DOI: https://doi.org/10.1134/S1023193507040040

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