Skip to main content
SpringerLink
Log in

Monitoring formation of poly(neutral red) film by EQCM

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

An electrochemical quartz crystal microbalance (EQCM) is employed for monitoring the growth of poly(neutral red) films on platinum in the electrolytic solution containing 5.0 mmol dm−3 neutral red, 0.3 mol dm−3 H2SO4, and 0.5 mol dm−3 Na2SO4. The in situ measurement of the frequency changes of the EQCM reveals that both the adsorption/desorption of neutral red and the formation of poly(neutral red) film can be observed together with anion sorption/desorption during the redox transformation of the polymer, and that the polymerization rate of neutral red increases slowly before the 11th cycle and then increases quickly with increasing number of potential cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Maricq, M.M., Waugh, J.S., MacDiarmid, A.G., Shirakawa, H., and Heeger, A.J., J. Am. Chem. Soc., 1978, vol. 100, p. 7729.

    Article  CAS  Google Scholar 

  2. Mu, S.L., Chen, C.X., and Wang, J.M., Synth. Met., 1997, vol. 88, p. 249.

    Article  CAS  Google Scholar 

  3. MacDiarmid, A.G., Chiang, J.C., Halpern, M., Huang, W.S., Mu, S.L., Somasiri, N.L.D., Wu, W.G., and Yaniger, S., Mol. Cryst., 1985, vol. 121, p. 173.

    CAS  Google Scholar 

  4. Genies, E.M. and Lapkowski, M., J. Electroanal. Chem., 1987, vol. 236, p. 189.

    Article  CAS  Google Scholar 

  5. Kanazawa, K.K., Diaz, A.F., Geiss, R.H., Gill, W.D., Kwak, J.F., Logan, J.A., Rabolt, J.F., and Street, G.B., J. Chem. Soc., Chem. Commun., 1979, p. 635.

  6. Genies, E.M., Bidan, G., and Diaz, A.F., J. Electroanal. Chem., 1983, vol. 49.

  7. Pei, Q. and Qian, R., Synth. Met., 1991, vol. 45, p. 35.

    Article  CAS  Google Scholar 

  8. Tourillon, G. and Garnier, F., J. Electroanal. Chem., 1982, vol. 135, p. 173.

    Article  CAS  Google Scholar 

  9. Tanaka, K., Shichiri, T., and Yamabe, T., Synth. Met., 1986, vol. 16, p. 207.

    Article  CAS  Google Scholar 

  10. Speight, J.G., Kovacic, P., and Koch, F.W., J. Macromol. Sci., 1971, vol. 5, p. 295.

    CAS  Google Scholar 

  11. Karyakin, A.A., Karyakina, E.E., and Schmidt, H.L., Electroanalysis, 1999, vol. 11, p. 149.

    Article  CAS  Google Scholar 

  12. Karyakin, A.A., Strakhova, A.K., Karyakina, E.E., Varfolomeyev, S.D., and Yatsimirsky, A.K., Bioelectrochem. Bioenerg., 1993, vol. 32, p. 35.

    Article  CAS  Google Scholar 

  13. Schlereth, D.D. and Karyakin, A.A., J. Electroanal. Chem., 1995, vol. 395, p. 221.

    Article  Google Scholar 

  14. Kertesz, V., Bacskai, J., and Inzelt, G., Electrochim. Acta, 1996, vol. 41, p. 2877.

    Article  CAS  Google Scholar 

  15. Shan, D., Mu, S.L., and Mao, B.W., Electroanalysis, 2001, vol. 13, p. 493.

    Article  CAS  Google Scholar 

  16. Chen, C.X. and Zhu, H.P., Bull. Electrochem., 2002, vol. 18, p. 247.

    CAS  Google Scholar 

  17. Chen, C.X. and Gao, Y.H., Mater. Lett., 2004, vol. 58, p. 3385.

    Article  CAS  Google Scholar 

  18. Orata, D. and Buttry, D.A., J. Am. Chem. Soc., 1987, vol. 109, p. 3574.

    Article  CAS  Google Scholar 

  19. Servagent, S. and Vieil, E., J. Electroanal. Chem., 1990, vol. 280, p. 227.

    Article  CAS  Google Scholar 

  20. Miras, M.C., Barbero, C., Kotz, R., and Haas, O., J. Electroanal. Chem., 1994, vol. 369, p. 193.

    Article  CAS  Google Scholar 

  21. Dai, H.P., Wu, Q.H., Sun, S.G., and Shiu, G.Q., J. Electroanal. Chem., 1998, vol. 456, p. 47.

    Article  CAS  Google Scholar 

  22. Zutic, V., Svetlicic, V., Clavilier, J., and Chevalet, J., J. Electroanal. Chem., 1987, vol. 219, p. 183.

    Article  CAS  Google Scholar 

  23. Sauerbrey, G., Z. Phys., 1959, vol. 155, p. 206.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Jiangsu University of Science and Technology, Zhenjiang, 212003, P. R. China

    C. Chen & Y. Gao

Authors
  1. C. Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Y. Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to C. Chen.

Additional information

Published in Russian in Elektrokhimiya, 2007, Vol. 43, No. 3, pp. 284–289.

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, C., Gao, Y. Monitoring formation of poly(neutral red) film by EQCM. Russ J Electrochem 43, 267–272 (2007). https://doi.org/10.1134/S1023193507030044

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193507030044

Key words

Search

Navigation