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Mechanism of metals’ electrodeposition from complex electrolytes allowing for the anions’ adsorption: Effect of the position of ligands and complex ions in the compact layer on the reaction orders

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Abstract

Effect of the relative position in the compact layer of specifically adsorbed electroactive complex ion and complexing ligand on the magnitude of current is considered. Effect of parameters that characterize the adsorption of such ions and the electrical double layer structure on the dependence of current on the solution composition and effective reaction orders is analyzed.

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References

  1. Rogozhnikov, N.A., Elektrokhimiya, 1995, vol. 31, p. 204.

    Google Scholar 

  2. Rogozhnikov, N.A., Elektrokhimiya, 1998, vol. 34, p. 1294.

    Google Scholar 

  3. Rogozhnikov, N.A., Elektrokhimiya, 1995, vol. 31, p. 588.

    Google Scholar 

  4. Rogozhnikov, N.A., Elektrokhimiya, 2005, vol. 41, p. 817.

    Google Scholar 

  5. Bliznakov, G. and Lasarov, D., Dokl. Bolg. Akad. Nauk, 1962, vol. 15, p. 57.

    CAS  Google Scholar 

  6. Vitanov, T. and Popov, A., Abstracts of Papers, ISE 28th Ann. Meet., Varna-Druzhba, 1977, vol. 1, p. 230.

  7. Rogozhnikov, N.A. and Bek, R.Yu., Elektrokhimiya, 1980, vol. 16, p. 662.

    CAS  Google Scholar 

  8. Rogozhnikov, N.A. and Bek, R.Yu., Elektrokhimiya, 1988, vol. 24, p. 839.

    CAS  Google Scholar 

  9. Delahay, P., Double Layer and Electrode Kinetics, New York: Wiley Interscience, 1965.

    Google Scholar 

  10. Pal’m, U.V. and Damaskin, B.B., Itogi Nauki Tekh., Ser: Elektrokhim., 1977, vol. 12, p. 121.

    Google Scholar 

  11. Wroblowa, H., Kovać, Z., and Bockris, J.O’M., Trans. Faraday Soc., 1965, vol. 61, p. 1523.

    Article  CAS  Google Scholar 

  12. Lawrence, J. and Parsons, R., J. Electroanal. Chem., 1968, vol. 16, p. 193.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Siberian Division, Russian Academy of Sciences, ul. Michurina 15, Novosibirsk, 630091, Russia

    N. A. Rogozhnikov

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  1. N. A. Rogozhnikov
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Correspondence to N. A. Rogozhnikov.

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Original Russian Text © N. A. Rogozhnikov, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 2, pp. 228–233.

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Rogozhnikov, N.A. Mechanism of metals’ electrodeposition from complex electrolytes allowing for the anions’ adsorption: Effect of the position of ligands and complex ions in the compact layer on the reaction orders. Russ J Electrochem 43, 217–222 (2007). https://doi.org/10.1134/S1023193507020103

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  • DOI: https://doi.org/10.1134/S1023193507020103

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