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Growth dynamics and structural variations of a friable metal deposit during its contact deposition from aqueous solutions

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Abstract

A model is proposed for describing dynamics of contact exchange of metals, which takes into account the side process of hydrogen evolution. The contact exchange dynamics and structural characteristics of the deposit are considered as functions of the concentration of ions that undergo reduction in solution and the cementation EMF. The consideration makes allowance for different densities of microelements and the effect of the solution stirring by hydrogen evolving concurrently.

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References

  1. Rotinyan, A.L. and Kheifets, V.L., Teoreticheskie osnovy kontaktnogo vytesneniya metallov: Konspekt Lektsii (Theoretical Foundations for Contact Deposition of Metals: A Synopsis of Some Lectures), Leningrad: Leningr. Khim.-Technol. Inst., 1979.

    Google Scholar 

  2. Alkatsev, M.I., Protsessy tsementatsii v tsvetnoi metallurgii (The Cementation Processes in the Metallurgy of Nonferrous Metals), Moscow: Metallurgiya, 1981.

    Google Scholar 

  3. Zelikman, A.N., Vol’dman, G.M., and Belyaevskaya, L.V., Teoriya gidrometallurgicheskikh protsessov (A Theory for the Hydrometallurgical Processes), Moscow: Metallurgiya, 1983.

    Google Scholar 

  4. Kakovskii, I.A. and Naboichenko, S.S., Termodinamika i kinetika gidrometallurgicheskikh protsessov (The Thermodynamics and Kinetics of the Hydrometallurgical Processes), Alma-Ata: Nauka, 1986.

    Google Scholar 

  5. Karbasov, B.G., Ustinenkova, L.E., and Tikhonov, K.I., Elektrokhimiya, 1997, vol. 33, p. 602.

    Google Scholar 

  6. Antropov, L.I. and Donchenko, M.I., Itogi Nauki Tekh., Ser: Korr. Zashch. Korr., 1973, vol. 2, p. 113.

    CAS  Google Scholar 

  7. Murashova, I.B., Vetrova, N.V., and Terent’ev, D.I., Elektrokhimiya, 1994, vol. 30, p. 1081.

    Google Scholar 

  8. Murashova, I.B. and Ostarkova, G.V., Elektrokhimiya, 2001, vol. 37, p. 975.

    Google Scholar 

  9. Murashova, I.B., Darintseva, A.B., and Gorelkina, P.A., Vestn. Ural Gos. Tekhn. Univ., Ser. Khim., 2003, no. 3, p. 112.

  10. Artamonov, V.P. and Pomosov, A.V., Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall., 1976, no. 3, p. 30.

  11. Darintseva, A.B., Murashova, I.B., Artamonov, V.V., and Gorelkina, P.A., Vestn. PGTU, 2003, no. 9, p. 134.

  12. Murashova, I.B., Taushkanov, P.V., and Burkhanova, N.G., Elektrokhimiya, 1999, vol. 35, p. 835.

    Google Scholar 

  13. Milchev, A., Stoyanov, S., and Kaishev, R., Elektrokhimiya, 1977, vol. 13, p. 855.

    CAS  Google Scholar 

  14. Milchev, A., Electrocrystallization: Fundamentals of Nucleation and Growth, Boston: Kluwer Academic, 2002.

    Google Scholar 

  15. Vogt, H., Surf. Technol., 1982, vol. 17, p. 301.

    Article  CAS  Google Scholar 

  16. Yakubova, T.V. and Murashova, I.B., Elektrokhimiya, 1995, vol. 31, p. 483.

    Google Scholar 

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Correspondence to I. B. Murashova.

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Original Russian Text © A.B. Darintseva, I.B. Murashova, V.V. Artamonov, V.P. Artamonov, 2007, published in Elektrokhimiya, 2007, Vol. 43, No. 2, pp. 165–173.

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Darintseva, A.B., Murashova, I.B., Artamonov, V.V. et al. Growth dynamics and structural variations of a friable metal deposit during its contact deposition from aqueous solutions. Russ J Electrochem 43, 157–166 (2007). https://doi.org/10.1134/S1023193507020048

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  • DOI: https://doi.org/10.1134/S1023193507020048

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