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Electrochemical iodination of C-methyl derivatives of dodecahydro-7,8-dicarba-nido-undecaborate anion

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Abstract

By electrochemical iodination of potassium 7-methyl-7,8-dicarba-nido-undecaborate and potassium 7,8-dimethyl-7,8-dicarba-nido-undecaborate, their monoiodine derivatives (extracted as tetramethylammonium salts) are synthesized. Their structure is confirmed by NMR and IR spectra and also by elemental analysis data.

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Authors and Affiliations

  1. Institute of Physical Organic Chemistry, Belarussian Academy of Sciences, Minsk, 220072, Belarus

    D. A. Rudakov, V. L. Shirokii, V. I. Potkin & E. A. Dikusar

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia

    V. I. Bragin, P. V. Petrovskii, I. B. Sivaev & V. I. Bregadze

  3. State Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, Russia

    A. V. Kisin

Authors
  1. D. A. Rudakov
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  2. V. L. Shirokii
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  3. V. I. Potkin
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  4. E. A. Dikusar
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  5. V. I. Bragin
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  6. P. V. Petrovskii
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  7. I. B. Sivaev
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  8. V. I. Bregadze
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  9. A. V. Kisin
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Corresponding author

Correspondence to V. L. Shirokii.

Additional information

Original Russian Text © D.A. Rudakov, V.L. Shirokii, V.I. Potkin, E.A. Dikusar, V.I. Bragin, P.V. Petrovskii, I.B. Sivaev, V.I. Bregadze, A.V. Kisin, 2006, published in Elektrokhimiya, 2006, Vol. 42, No. 3, pp. 324–328.

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Rudakov, D.A., Shirokii, V.L., Potkin, V.I. et al. Electrochemical iodination of C-methyl derivatives of dodecahydro-7,8-dicarba-nido-undecaborate anion. Russ J Electrochem 42, 280–284 (2006). https://doi.org/10.1134/S102319350603013X

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  • DOI: https://doi.org/10.1134/S102319350603013X

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