Abstract
The average size of copper particles in copper-containing electron-ion exchangers is determined with the aid of microscopy and x-ray diffractometry. The results are used to calculate the contribution made by a dimensional factor to the electrode potential. Compared to the potential of compact copper, the potential shift in the negative direction measured experimentally falls within the region of calculated values. The average size of copper particles remains practically unchanged after contact with a copper sulfate solution, testifying to stabilization of an ultradisperse state of copper particles by a polymer matrix.
Similar content being viewed by others
References
Klabunde, K.J., Free Atoms, Clusters and Nanoscale Particles, New York: Academic, 1994.
Pomogailo, A.D., Rozenberg, A.S., and Uflyand, I.E., Nanochastitsy metallov v polimerakh (Nanosized Metal Particles in Polymers), Moscow: Khimiya, 2000.
Uvarov, N.F. and Boldyrev, V.V., Usp. Khim., 2001, vol. 70, p. 307.
Petrii, O.A. and Tsirlina, G.A., Usp. Khim., 2001, vol. 70, p. 330.
Sergeev, G.B., Nanokhimiya (Nanochemistry), Moscow: Mosk. Gos. Univ., 2003.
Uaitsaids, Dzh., Khigler, D., and Andres, R., Nanotekhnologiya v blizhaishem desyatiletii: Prognoz napravleniya issledovanii (Nanotechnology in the Nearest Decade: A Prognosis of the Research Direction), Roko, M.K., Uil’yams, R.S., and Alivisatos, P., Eds., Moscow: Mir, 2002.
Cizek, Ja., Prochazka, I., Cieslar, M., Kuzel, R., Kuriplach, Ja., Chmelik, F., Stulikova, I., Besvar, F., Melikhova, O., and Islamgaliev, R.K., Phys. Rev. B, 2002, vol. 65, p. 094106.
Kravchenko, T.A. and Aristov, I.V., in Ion Exchange: Highlights of Russian Science, Muraviev, D., Gorshkov, V., and Warshawsky, A., Eds., New York: Marcel Dekker, 2000, vol. 1, p. 691.
Sviridov, V.V., Vorob’eva, T.N., Gaevskaya, T.V., and Stepanova, L.I., Khimicheskoe osazhdenie metallov iz vodnykh rastvorov (Electroless Metal Deposition from Aqueous Solutions), Minsk: Universitetskoe, 1987.
Vashkyalis, A., Elektrokhimiya, 1978, vol. 14, p. 1770
Plyasova, L.M., Molina, I.Yu., Cherepanova, S.V., Rudina, N.A., Sherstyuk, O.V., Savinova, E.R., Pron’kin, S.N., and Tsirlina, G.A., Elektrokhimiya, 2002, vol. 38, p. 1116.
Cerisier, M., Van Hesendonck, C., and Celis, J.-P., J. Electrochem. Soc., 1999, vol. 146, p. 1829.
Kravchenko, T.A., Sotskaya, N.V., and Krysanov, V.A., Zh. Fiz. Khim., 2001, vol. 75, p. 134.
Mirkin, A.I., Spravochnik po rentgenostrukturnomu analizu polikristallov (Handbook on X-ray Diffraction Analysis of Polycrystals), Moscow: Fizmatgiz, 1961.
Umanskii, Ya.S., Skakov, Yu.A., Ivanov, A.N., and Rastorguev, L.N., Kristallografiya, rentgenografiya i elektronnaya mikroskopiya (Crystallography, X-ray Diffractometry, and Electron Microscopy), Moscow: Metallurgiya, 1982.
Vol’f, I.V., Doctoral (Techn.) Dissertation, Leningrad: LTI TsBP, 1973.
Adamson, A.W., The Physical Chemistry of Surfaces, New York: Wiley, 1977, 3rd ed.
Fistul’, V.I., Fizika i khimiya tverdogo tela (The Physical Chemistry of Solids), Moscow: Metallurgiya, 1995.
Semenchenko, V.K., Poverkhnostnye yavleniya v metallakh i splavakh (The Surface Phenomena in Metals and Alloys), Moscow: Gostekhizdat, 1957.
Poltorak, O.M., Termodinamika v fizicheskoi khimii (Thermodynamics in Physical Chemistry), Moscow: Vysshaya Shkola, 1991.
Poltorak, O.M., Lektsii po khimicheskoi termodinamike (Lectures on Chemical Thermodynamics), Moscow: Vysshaya Shkola, 1971.
Novakovskii, V.M., Iksanov, B.A., Tolstaya, M.A., and Khokhlacheva, N.M., Zashch. Met., 1984, vol. 20, p. 565.
Tomashov, N.D., and Mikhailovskii, Yu.N., Trudy Vsessoyuz. Soveshch. po Elektrokhimii (Proc. All-Union Conf. on Electrochemistry), Moscow: Akad. Nauk SSSR, 1959.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.A. Kravchenko, V.A. Krysanov, A.S. Stolpovskii, G.A. Filatov, E.V. Zolotukhina, A.A. Zagorodnii, 2006, published in Elektrokhimiya, 2006, Vol. 42, No. 3, pp. 272–278.
Rights and permissions
About this article
Cite this article
Kravchenko, T.A., Krysanov, V.A., Stolpovskii, A.S. et al. Contribution of dimensional factor to the potential of copper-containing electron-ion exchangers. Russ J Electrochem 42, 233–238 (2006). https://doi.org/10.1134/S1023193506030049
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193506030049