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Kinetics and thermodynamics of the electrodeposition of palladium, thallium, and tellurium from different baths

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Abstract

Some kinetic and activation thermodynamic functions for the electrodeposition of palladium, thallium, and tellurium from the best selected baths, viz. niclosamide bath [5-chloro-N-(2-chloro-4-nitrophenyl)-2-hydroxybenzamide] for Pd, alizarin red bath for Tl, and salicylaldehyde bath for Te, are determined. Reaction rate constant (k), half-lifetime (t 1/2), activation energy (E a), and such activation thermodynamic parameters as entropy change (ΔS*), enthalpy change (ΔH*), and Gibbs free energy (ΔG*) are calculated by applying the rate theory of the first-order reaction and the Eyring theory of the reaction rate. The effect of temperature change in the range of 30–60°C on the above parameters is studied and thoroughly discussed. The effect of metal type on both the reaction rate and the activation energy is also investigated.

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Authors and Affiliations

  1. Mansoura University, P.O. Box 35516, Mansoura, Egypt

    A. A. El-Khouly, M. A. H. Hafez & I. M. M. Kenawy

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  1. A. A. El-Khouly
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  2. M. A. H. Hafez
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  3. I. M. M. Kenawy
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Additional information

Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 3, pp. 264–271.

The text was submitted by the authors in English.

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El-Khouly, A.A., Hafez, M.A.H. & Kenawy, I.M.M. Kinetics and thermodynamics of the electrodeposition of palladium, thallium, and tellurium from different baths. Russ J Electrochem 42, 225–232 (2006). https://doi.org/10.1134/S1023193506030037

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  • DOI: https://doi.org/10.1134/S1023193506030037

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