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Investigation of Structural and Optical Properties of Conductive Polymer Doped with Tin Oxide via in Situ Polymerization

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Abstract

The aim of this research is to manufacture a new hybrid material consisting of polypyrrole, poly(N-methyl pyrrole) and their copolymer as organic component and tin oxide as inorganic component. This hybrid materials are synthesized by in situ polymerization. The prepared nanocomposites are characterized by different methods (XRD, FTIR, and UV–Vis). The X-ray diffraction measurements reveal that the insertion of tin dioxide into the polymer improves its properties by changing the structure from amorphous to tetragonal rutile crystalline structure of SnO2. The optical gap values of pure SnO2 nanoparticles and nanocomposites with poly(N-methyl pyrrole), polypyrrole and their based copolymer are 4.28, 3.99, 3.94, and 3.86 eV, respectively.

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Funding

This work is funding by La Direction Générale de la Recherche Scientifique et du Développement Technologique (DGRSDT) Algeria.

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Correspondence to Abdelkader Dehbi.

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Alouche, B., Yahiaoui, A., Dehbi, A. et al. Investigation of Structural and Optical Properties of Conductive Polymer Doped with Tin Oxide via in Situ Polymerization. Polym. Sci. Ser. A 63, 865–871 (2021). https://doi.org/10.1134/S0965545X21350017

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  • DOI: https://doi.org/10.1134/S0965545X21350017

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