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Relaxation Behavior of Thermoplastic Polyimide R-BAPB in the Amorphous State

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Abstract

The molecular mobility of poly(4,4'-bis(4-aminophenoxy)biphenyl)imido-1,3-bis(3,3'-4,4'-dicarboxyphenoxy)benzene) films is studied by the thermally stimulated depolarization current (TSDC) technique and dielectric spectroscopy. The existence of two dipolar polarization relaxation regions (β and α) related to the local mobility in the glassy state and the cooperative segmental mobility in the rubbery state, respectively, is revealed. The temperature dependences of the relaxation time for the β-process obey the Arrhenius equation; for the α-process, they obey the Vogel–Tammann–Hesse equation. Emergence of the third peak βI is related to relaxation of the space homocharge. The molecular mechanisms of all the observed processes are revealed.

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REFERENCES

  1. R. G. Bryant, Polyimides (Wiley, New York, 2002).

    Google Scholar 

  2. C. E. Sroog, in Encyclopedia of Polymer Science and Technology, Ed. by H. Mark (Wiley, New York, 1969), Vol. 11, p. 247.

    Google Scholar 

  3. J. M. Perena, Angew. Makromol. Chem. 106, 61 (1982).

    Article  CAS  Google Scholar 

  4. V. E. Yudin and V. M. Svetlichnyi, Polym. Sci., Ser. C 58, 16 (2016).

    Article  CAS  Google Scholar 

  5. V. E. Yudin and V. M. Svetlichnyi, Ross. Khim. Zh. 53 (4), 75 (2009).

    CAS  Google Scholar 

  6. V. E. Yudin, V. M. Svetlichnyi, A. N. Shumakov, R. Schechter, H. Harel, and G. Marom, Composites, Part A 39, 85 (2008).

    Article  CAS  Google Scholar 

  7. P. Hedvig, Dielectric Spectroscopy of Polymers (Akademiai Kiado, Budapest, 1977).

    Google Scholar 

  8. E. Riande and R. Diaz-Calleja, Electrical Properties of Polymers (Marcel Dekker, Inc., New York, 2004).

    Book  Google Scholar 

  9. Z. Sun, L. Dong, Y. Zhuang, L. Cao, M. Ding, and Z. Feng, Polymer 33, 4728 (1992).

    Article  CAS  Google Scholar 

  10. S. Z. D. Cheng, T. M. Chalmes, Y. Gu, Y. Yoon, F. W. Harris, J. Cheng, M. Fone, and J. L. Koenig, Macromole. Chem. Phys. 196, 1439 (1995).

    Article  CAS  Google Scholar 

  11. S. Chisca, V. E. Musteata, I. Sava, and M. Bruma, Eur. Polym. J. 47, 1176 (2011).

    Article  CAS  Google Scholar 

  12. J. D. Jacobs, M. J. Arlen, D. H. Wang, Z. Ounaies, R. Berny, L. Tan, P. H. Garrett, and R. A. Vaia, Polymer 51, 3139 (2010).

    Article  CAS  Google Scholar 

  13. M. S. Gaur and R. K. Tiwari, J. Plast. Film Sheeting 25, 271 (2009).

    Article  CAS  Google Scholar 

  14. S. X. Lu, P. Cebe, and M. Capel, J. Appl. Polym. Sci. 57, 1359 (1995).

    Article  CAS  Google Scholar 

  15. V. M. Svetlichnyi and V. V. Kudryavtsev, Polym. Sci., Ser. B 45, 140 (2003).

    Google Scholar 

  16. V. E. Smirnova, I. V. Gofman, E. M. Ivan’kova, A. L. Didenko, A. V. Krestinin, G. I. Zvereva, V. M. Svetlichnyi, and V. E. Yudin, Polym. Sci., Ser. A 55, 268 (2013).

    Article  CAS  Google Scholar 

  17. V. E. Yudin, V. M. Svetlichnyi, G. N. Gubanova, A. I. Grigor’ev, T. E. Sukhanova, I. V. Gofman, A. L. Didenko, E. N. Popova, G. N. Fedorova, and V. V. Kudryavtsev, Polym. Sci., Ser. A 44, 148 (2002).

    Google Scholar 

  18. M. E. Borisova, A. M. Kamalov, V. E. Smirnova, and V. E. Yudin, Polym. Sci., Ser. A 60, 278 (2018).

    Article  CAS  Google Scholar 

  19. J. van Turnhout, Polym. J. 2, 173 (1971).

    Article  CAS  Google Scholar 

  20. P. K. Khare, J. M. Keller, and S. C. Datt, Bull. Mater. Sci. 22, 109 (1999).

    Article  CAS  Google Scholar 

  21. A. Tiwari, A. K. Gupta, R. Bajpai, and J. M. Keller, Indian J. Phys., A 85, 1581 (2011).

    CAS  Google Scholar 

  22. M. E. Borisova and S. N. Koikov, Physics of Dielectrics (LGU, Leningrad, 1979) [in Russian].

    Google Scholar 

  23. S. Havriliak and S. Negami, Polymer 8, 161 (1967).

    Article  CAS  Google Scholar 

  24. S. U. Vallerien, F. Kremer, and C. Boeffel, Liq. Cryst. 4, 79 (1989).

    Article  CAS  Google Scholar 

  25. R. Diaz-Calleja, Macromolecules 33, 8924 (2000).

    Article  CAS  Google Scholar 

  26. D. H. Vogel, Phys. Z. 22, 645 (1921).

    CAS  Google Scholar 

  27. E. Donth, The Glass Transition: Relaxation Dynamics in Liquids and Disopdered Materials (Springer, Berlin, 2001).

    Book  Google Scholar 

  28. J. F. Mano and J. J. Mura-Ramos, Thermochim. Acta 323, 65 (1998).

    Article  CAS  Google Scholar 

  29. J. J. Mura-Ramos and J. F. Mano, Thermochim. Acta 285, 347 (1996).

    Article  Google Scholar 

  30. A. Boersma, J. van Turnhout, and M. Wubbenhorst, Macromolecules 31, 7453 (1998).

    Article  CAS  Google Scholar 

  31. M. Fu, L. A. Dissado, G. Chen, and J. Fothergill, IEEE Trans. Dielectr. Electr. Insul. 15, 851 (2008).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Peter the Great St. Petersburg Polytechnic University, 195251, St. Petersburg, Russia

    A. M. Kamalov & M. E. Borisova

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    A. L. Didenko, N. A. Nikonorova, V. M. Svetlichnyi, V. E. Smirnova & V. E. Yudin

  3. Russian State Pedagogical University, 191186, St. Petersburg, Russia

    R. A. Castro

Authors
  1. A. M. Kamalov
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  2. M. E. Borisova
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  3. A. L. Didenko
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  4. N. A. Nikonorova
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  5. V. M. Svetlichnyi
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  6. V. E. Smirnova
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  7. R. A. Castro
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  8. V. E. Yudin
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Correspondence to A. M. Kamalov.

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Translated by T. Soboleva

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Kamalov, A.M., Borisova, M.E., Didenko, A.L. et al. Relaxation Behavior of Thermoplastic Polyimide R-BAPB in the Amorphous State. Polym. Sci. Ser. A 62, 107–115 (2020). https://doi.org/10.1134/S0965545X20010058

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  • DOI: https://doi.org/10.1134/S0965545X20010058

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