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AC Impedance Analysis of Lithium Ion Based PEO:PVP Solid Polymer Blend Electrolytes

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Abstract

Lithium ion conducting poly(ethylene oxide) (PEO):poly(vinyl pyrrolidone) (PVP) polymer blend electrolytes have been prepared by solution casting technique. The XRD and FTIR analysis confirm the complexation between salt and polymers. The conductivity of the samples is analyzed by impedance spectroscopy technique within the frequency range of 42 Hz to 1 MHz in the temperature range of 303 to 363 K. The conductivity of polymer electrolytes increases up to 20 wt % of lithium acetate concentration and the higher conductivity is found to be 2.56 × 10–6 S/cm at room temperature. The transference number measurements are also carried out using Wagner polarization technique.

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Authors and Affiliations

  1. Multi-functional Materials Laboratory/International Research Center, Kalasalingam Academy of Research and Education, 626 126, Tamilnadu, Krishnankoil, India

    K. Sundaramahalingam

  2. Department of Physics/School of Advanced Sciences, Kalasalingam Academy of Research and Education, 626 126, Tamilnadu, Krishnankoil, India

    M. Muthuvinayagam & N. Nallamuthu

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  1. K. Sundaramahalingam
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  2. M. Muthuvinayagam
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  3. N. Nallamuthu
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Correspondence to M. Muthuvinayagam.

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Sundaramahalingam, K., Muthuvinayagam, M. & Nallamuthu, N. AC Impedance Analysis of Lithium Ion Based PEO:PVP Solid Polymer Blend Electrolytes. Polym. Sci. Ser. A 61, 565–576 (2019). https://doi.org/10.1134/S0965545X19050171

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