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Sizes of Macromolecules of Copolymers of N-Methyl-N-Vinylacetamide and N-Methyl-N-Vinylamine Hydrochloride with Low Charge Linear Density

  • Polyelectrolytes
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Abstract

Series of copolymers of N-methyl-N-vinylacetamide and N-methyl-N-vinylamine hydrochloride containing from 1.5 to 17% mol % of charged units were obtained by partial hydrolysis of poly(N-methyl-N-vinylacetamide). A complex of hydrodynamic investigations of their diluted solutions (viscous flow, velocity sedimentation, translational diffusion) was performed in 0.2 M NaCl in order to determine the molecular characteristics of copolymers. Viscosimetric investigations were performed in salt-free solution (ionic strength ~10–6 M) to study intrachain electrostatic interactions; the influence of charge linear density on the sizes of polyelectrolyte macromolecules was studied under these conditions. The examination of hydrodynamic volumes, equilibrium rigidity, and/or swelling coefficients of charged chains was performed.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, SSt. Petersburg, 199004, Russia

    G. M. Pavlov, O. A. Dommes, A. A. Gosteva, O. V. Okatova, I. I. Gavrilova & E. F. Panarin

  2. St. Petersburg State University, SSt. Petersburg, 199034, Russia

    G. M. Pavlov

  3. Peter the Great St. Petersburg Polytechnic University, St. Petersburg, 195251, Russia

    E. F. Panarin

Authors
  1. G. M. Pavlov
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  2. O. A. Dommes
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  3. A. A. Gosteva
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  4. O. V. Okatova
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  5. I. I. Gavrilova
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  6. E. F. Panarin
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Correspondence to G. M. Pavlov.

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Original Russian Text © G.M. Pavlov, O.A. Dommes, A.A. Gosteva, O.V. Okatova, I.I. Gavrilova, E.F. Panarin, 2018, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2018, Vol. 60, No. 2, pp. 127–133.

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Pavlov, G.M., Dommes, O.A., Gosteva, A.A. et al. Sizes of Macromolecules of Copolymers of N-Methyl-N-Vinylacetamide and N-Methyl-N-Vinylamine Hydrochloride with Low Charge Linear Density. Polym. Sci. Ser. A 60, 172–178 (2018). https://doi.org/10.1134/S0965545X18020116

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  • DOI: https://doi.org/10.1134/S0965545X18020116

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