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Dielectric properties of films of Ag-ED20 epoxy nanocomposite synthesized in situ. Temperature dependence of direct current conductivity

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Abstract

The influence of silver myristate used as a precursor of silver nanoparticles on the direct current conductivity σ dc of epoxy polymer within the concentration range of ≤0.8 wt % was investigated. The value of direct current conductivity was determined on the basis of analysis of the frequency dependence of complex permittivity within the frequency range of 10−2–105 Hz. The temperature dependence of σ dc is composed of two regions. The dependence corresponds to the Vogel-Fulcher-Tammann empirical law σ dc = σ dc0exp{‒DT 0/(T-T 0)} (where T 0 is the Vogel temperature and D is the strength parameter) at temperatures higher than the glass transition temperature T g. At the same time, T 0 does not depend on the concentration of nanoparticles. The Arrhenius temperature dependence characterized by activation energy about 1.2 eV is observed at temperatures lower than T g. The observed shape of the temperature dependence is related to the change in the mechanism of conductivity after “freezing” of ionic mobility at temperatures lower than T g. The value of σ dc is increased as the concentration of nanoparticles is raised within the temperature range of T > T g. The obtained dependence of σ dc on silver myristate concentration is similar to the root one, indicating the absence of percolation within the studied range of concentrations.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    G. F. Novikov, E. V. Rabenok, L. M. Bogdanova & V. I. Irzhak

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  1. G. F. Novikov
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  2. E. V. Rabenok
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  3. L. M. Bogdanova
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  4. V. I. Irzhak
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Correspondence to G. F. Novikov.

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Original Russian Text © G.F. Novikov, E.V. Rabenok, L.M. Bogdanova, V.I. Irzhak, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2017, Vol. 59, No. 5, pp. 447–456.

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Novikov, G.F., Rabenok, E.V., Bogdanova, L.M. et al. Dielectric properties of films of Ag-ED20 epoxy nanocomposite synthesized in situ. Temperature dependence of direct current conductivity. Polym. Sci. Ser. A 59, 741–750 (2017). https://doi.org/10.1134/S0965545X17050145

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  • DOI: https://doi.org/10.1134/S0965545X17050145

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