Abstract
On the basis of the reptation theory, this paper discusses the shear-rate-associated transition of a polymer-fluid structure formed by topological polymer-chain crosslinks to a new steady-state condition. Structure-characterizing ratio z of the current number of polymer chain Kuhn segments between effective along-chain crosslinks to the steady-state value of this number is introduced. The recurrence equation z n + 1 ∼ Wi · z n (1 − z n ) + z n is calculated to describe the transition through period-doubling bifurcations from the steady-state condition (z → 1) to the chaotic behavior of z values with an increase in the Weissenberg number (Wi). This transition should cause flow instability and the development of the so-called elastic turbulence of polymer fluids at low Reynolds numbers. Specific examples are used to show that the suggested scenario can be confirmed both qualitatively and quantitatively with the published experimental data on the development of elastic turbulence of polymer fluids.
Similar content being viewed by others
References
P. G. de Gennes, Scaling Concepts in Polymer Physics (Cornell. Univ. Press, Ithaka, 1979).
A. Yu. Grosberg and A. R. Khokhlov, Physics in Polymer World (Nauka, Moscow, 1989) [in Russian].
X. Yang, S.-Q. Wang, A. Halasa, and H. Ishida, Rheol. Acta 37, 415 (1998).
P. Tapadia and S.-Q. Wang, Macromolecules 37, 9083 (2004).
S. Ravindranath and S.-Q. Wang, J. Rheol. 52, 957 (2008).
A. Ya. Malkin, Polym. Sci., Ser. A 51(1), 80 (2009).
G. V. Vinogradov and A. Ya. Malkin, Rheology of Polymers (Khimiya, Moscow, 1977) [in Russian].
R. M. May, Nature 261, 459 (1976).
M. J. Feigenbaum, J. Stat. Phys. 19, 25 (1978).
I. Prigogine and I. Stengers, Order out of Chaos: Man’s New Dialogue with Nature (Bentam, New York, 1984).
G. Astarita and G. Marrucci, Principles of Non-Newtonian Fluid Mechanics (McGraw-Hill, London, 1974).
V. N. Kalashnikov, Polymer Solution Flow by Tubes with Variable Cross-Section (Institut problem mekhaniki AN SSSR, Moscow, 1980) [in Russian].
V. N. Kalashnikov and A. N. Askarov, Viscoelastic Properties of Dissolved Solutions of High-molecular Polymers: Measurement of Natural Time (Institut problem mekhaniki AN SSSR, Moscow, 1986) [in Russian].
M. G. Tsiklauri, Inzh.-Fiz. Zh. 66(3), 267 (1994).
A. Groisman and V. Steinberg, Nature 405(4), 53 (2000).
A. Groisman and V. Steinberg, New J. Phys. 6, 29 (2004).
A. N. Morozov and W. Van Saarloos, Phys. Rep., No. 447, 112 (2007).
A. Ya. Malkin, A. V. Semakov, and V. G. Kulichikhin, Polym. Sci., Ser. A 52(11), 1083 (2010).
A. S. Lodge, Elastic Liquids (Acad. Press, London 1964).
V. N. Kalashnikov, in Proceedings of International School-Seminar “Heat and Mass Exchange in Polymer Systems and Suspensions,” Minsk, Belarus, 1984 (Inst. teplo- i massoobmena im. A.V. Lykova, AN BSSR, Minsk, 1984), Vol. 1, p. 48.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.V. Vasil’chenko, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 4, pp. 368–372.
Rights and permissions
About this article
Cite this article
Vasil’chenko, S.V. Scenario of the development of elastic turbulence of polymer fluids. Polym. Sci. Ser. A 57, 489–493 (2015). https://doi.org/10.1134/S0965545X15040148
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X15040148