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Influence of the types and concentrations of exchangeable ions on the state of crosslinked organic polyelectrolyte-water systems

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Abstract

The dependences of the amounts of hydration water and “free” water in equilibrium water-swollen crosslinked organic polyelectrolytes—namely, the sulfonated copolymer of styrene and 8 wt % divinylbenzene, cationite KRS-8p, and the copolymer of poly(acrylic acid) and 6 wt % ethylene glycol dimethacrylate, cationite Biocarb-A—on the degree of replacement of hydrogen ions in ionogenic groups with Na+, K+, Mg++, Ca++, Co++, and Zn++ in the range 270–333 K are determined. Their relaxation transitions from the glassy state to the rubbery state are studied. Glass-transition temperatures for various mixed salt forms of these cationites are measured. Patterns of dependences of the equilibrium amounts of hydration water and the glass-transition temperatures of swollen cationites on the types and concentrations of exchangeable ions are ascertained. The relaxation states and phase compositions of the studied cationite-water systems are determined.

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References

  1. I. B. Rabinovich and E. A. Krylov, Vysokomol. Soedin., Ser. A 27(2), 387 (1985).

    CAS  Google Scholar 

  2. I. B. Rabinovich and E. A. Krylov, Russ. J. Phys. Chem. A 73(5), 814 (1999).

    Google Scholar 

  3. E. A. Krylov, Russ. J. Phys. Chem. A 73(5), 708 (1999).

    Google Scholar 

  4. E. A. Krylov, A. V. Makarov, I. B. Rabinovich, N. V. Karyakin, S. V. Burovtseva, Russ. J. Phys. Chem. A 76(7), 1139 (2002).

    Google Scholar 

  5. N. G. Polyanskii, G. V. Gorbunovand, and N. L. Polyanskaya, Methods for Ion-Exchanger Studies (Khimiya, Moscow, 1976).

    Google Scholar 

  6. E. A. Krylov, Doctoral Dissertation in Chemistry (Nizhnegorodskii gos. tekhn. un-t, Nizhnii Novgorod, 1997).

  7. A. V. Makarov, Candidate’s Dissertation in Chemistry (Nizhnegorodskii gos. tekhn. un-t, Nizhnii Novgorod, 2004).

  8. Thermal Constants of Compounds, Ed. by V. P. Glushko (AN SSSR, Moscow, 1965) [in Russian].

    Google Scholar 

  9. G. S. Libinson, Physico-Chemical Properties of Carboxylic Cationites (Nauka, Moscow, 1969) [in Russian].

    Google Scholar 

  10. L. K. Shataeva, N. N. Kuznetsova, and G. E. El’kin, Carboxylic Cation Exhangers in Biology (Nauka, Leningrad, 1979) [in Russian].

    Google Scholar 

  11. K. B. Yatsimirskii, Zh. Anal. Khim. 6, 211 (1951).

    CAS  Google Scholar 

  12. V. A. Kargin and N. F. Bakeev, Kolloidn. Zh. 19(2), 133 (1957).

    CAS  Google Scholar 

  13. V. A. Kargin, A. A. Efendiev, and Z. Ya. Berestneva, Dokl. Akad. Nauk SSSR 155(6), 1401 (1964).

    CAS  Google Scholar 

  14. A. A. Efendiev and A. T. Shakhtakhtinskaya, Vysokomol. Soedin., Ser. A 20(2), 314 (1978).

    CAS  Google Scholar 

  15. A. I. Rusanov, Phase Equilibria and Surface Phenomena (Khimiya, Leningrad, 1967) [in Russian].

    Google Scholar 

  16. I. B. Rabinovich, A. N. Mochalov, I. Ya. Tsvetkova, T. B. Khlystova, Ye. M. Moseyeva, V. A. Maslova, Acta Polym. 34(8), 482 (1983).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Research Institute of Chemistry, Nizhny Novgorod State University, pr. Gagarina 23, korp. 5, Nizhny Novgorod, 603950, Russia

    E. A. Krylov, N. I. Mashin, N. I. Sirotkin, A. A. Tumanov & E. A. Cherniaeva

Authors
  1. E. A. Krylov
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  2. N. I. Mashin
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  3. N. I. Sirotkin
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  4. A. A. Tumanov
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  5. E. A. Cherniaeva
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Correspondence to E. A. Krylov.

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Original Russian Text © E.A. Krylov, N.I. Mashin, N.I. Sirotkin, A.A. Tumanov, E.A. Cherniaeva, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 4, pp. 287–294.

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Krylov, E.A., Mashin, N.I., Sirotkin, N.I. et al. Influence of the types and concentrations of exchangeable ions on the state of crosslinked organic polyelectrolyte-water systems. Polym. Sci. Ser. A 57, 375–382 (2015). https://doi.org/10.1134/S0965545X15040082

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  • DOI: https://doi.org/10.1134/S0965545X15040082

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