Polymer Science Series A

, Volume 57, Issue 2, pp 177–185 | Cite as

Miscibility and rheological properties of epoxy resin blends with aromatic polyethers

  • M. P. Arinina
  • S. O. Ilyin
  • V. V. Makarova
  • I. Yu. Gorbunova
  • M. L. Kerber
  • V. G. Kulichikhin
Polymer Blends

Abstract

The miscibility of the bisphenol A epoxy oligomer with a number of aromatic polyethers is studied via optical interferometry. It is shown that polysulfone and polycarbonate are unlimitedly soluble in the oligomer. The dissolution of polycarbonate is accompanied by a chemical interaction and the formation of a new phase. For poly(ether sulfone) and poly(ether imide), amorphous phase separations with the LCST and the UCST, respectively, are observed. The polymer solutions are Newtonian liquids, and the systems in which phase separation occur feature the yield stress. A shift of the phase-equilibrium lines during the action of shear is revealed.

Keywords

Rheological Property Polymer Science Series Normal Stress Difference Newtonian Liquid Epoxy Oligomer 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • M. P. Arinina
    • 1
  • S. O. Ilyin
    • 1
  • V. V. Makarova
    • 1
  • I. Yu. Gorbunova
    • 2
  • M. L. Kerber
    • 2
  • V. G. Kulichikhin
    • 1
  1. 1.Topchiev Institute of Petrochemical SynthesisRussian Academy of SciencesMoscowRussia
  2. 2.Mendeleev University of Chemical TechnologyMoscowRussia

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