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Relaxation inhomogeneity of the structure of latex polymers modified with water-soluble phthalocyanine

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Abstract

The possibility to quantitatively analyze change in the relaxation microinhomogeneity of latex polymers during variation in the method of their preparation and modification with ionic phthalocyanine has been shown. The probability of estimating the width of the continuous relaxation-time spectra via comparison of the temperature dependences of the given internal-friction spectra and the temperature dependence of variation in the discrete relaxation time of the α process has been demonstrated. The correlation between the temperature-frequency variations of the polymeric relaxation modulus of the systems under the free-oscillation regime and the degree of their relaxation microinhomogeneity has been considered.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    T. R. Aslamazova, V. A. Lomovskoy & A. Yu. Tsivadze

Authors
  1. T. R. Aslamazova
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  2. V. A. Lomovskoy
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  3. A. Yu. Tsivadze
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Correspondence to T. R. Aslamazova.

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Original Russian Text © T.R. Aslamazova, V.A. Lomovskoy, A.Yu. Tsivadze, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 5, pp. 501–508.

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Aslamazova, T.R., Lomovskoy, V.A. & Tsivadze, A.Y. Relaxation inhomogeneity of the structure of latex polymers modified with water-soluble phthalocyanine. Polym. Sci. Ser. A 56, 579–586 (2014). https://doi.org/10.1134/S0965545X14050010

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  • DOI: https://doi.org/10.1134/S0965545X14050010

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