Abstract
It is established via an X-ray method that the preparation of powdered forms of cellulose under the action of Lewis acids on fibrous hardwood cellulose is accompanied by a change in its crystallographic characteristics. The degrees of crystallinity, the sizes of crystallites, and the periods and monoclinic angles of the unit cells of the obtained powdered celluloses were determined.
Similar content being viewed by others
References
Cellulose and Its Derivatives, Ed. by N. Bikales and L. Segal (Wiley, New York, 1971; Mir, Moscow, 1974).
B. Wunderlich, Macromolecular Physics, Vol. 1: Crystal Structure, Morphology, Defects (Academic, New York, 1973; Mir, Moscow, 1976).
V. M. Nikitin, A. V. Obolenskaya, and V. P. Shchegolev, Chemistry of Wood and Cellulose (Lesnaya Promyshlennost, Moscow, 1978) [in Russian].
A. C. Sullivan, Cellulose 4, 181 (1997).
S. V. Frolova, Candidate’s Dissertation in Chemistry (Ivanovo, 2009).
R. I. Sarybaeva, T. V. Vasil’kova, and V. A. Afanas’ev, Izv. Akad. Nauk Kirgizsk. SSR, No. 2, 42 (1979).
N. V. Melekh, Candidate’s Dissertation in Mathematics and Physics (Petrozavodsk, 2008).
Yu. V. Karyakin and I. I. Angelov, Pure Chemical Reagents (Khimiya, Moscow, 1974) [in Russian].
S. V. Frolova, L. A. Kuvshinova, and A. V. Kuchin, RF Patent No. 2478664 (2013).
S. V. Frolova and V. A. Demin, Russ. J. Appl. Chem. 81, 152 (2008).
V. V. Petrova, X-Ray Diffraction Analysis of Cellulose (Petrozavodsk. Gos. Univ., Petrozavodsk, 1994) [in Russian].
L. A. Aleshina and O. N. Shivrin, X-Ray Analysis of Crystals (Petrozavodsk. Gos. Univ., Petrozavodsk, 2004) [in Russian].
L. A. Aleshina, N. V. Melekh, and A. D. Fofanov, Khim. Rastit. Syr’ya, No. 3, 31 (2005).
Program “Ritveld Method” 2006610292, March 27, 2006. Program Complex PDWin-4.0 (Nauchno-Proizvod. Predpriyatie “Burevestnik”, St. Petersburg, 2004) [in Russian].
L. A. Aleshina, L. A. Lugovskaya, A. S. Filatov, A. D. Fofanov, S. V. Glazkova, and M. V. Podoinikova, http://Zhurnal.Ape.Relarn.Ru/Articles/2002, 203.
N. V. Melekh and L. A. Aleshina, Estestv. Tekh. Nauki, No. 3, 37 (2011).
A. D. French and P. S. Howley, in Proceedings of 10 Cellulose Conference “Cellulose and Wood: Chemistry and Technology”, 1989, p. 159.
W. Claffey and J. Blackwell, Biopolymers 15, 1903 (1976).
Y. Nishiyama, J. Sugiyama, H. Chanzy, and P. Langan, J. Am. Chem. Soc., No. 125, 14300 (2003).
L. A. Aleshina, N. V. Melekh, and S. V. Frolova, in Proceedings of 5 All-Russia Scientific Conference (Syktyvkar-Ufa, 2008), p. 21.
O. A. Battista and P. A. Smith, Ind. Eng. Chem. 54, 20 (1962).
N. I. Nikitin, Chemistry of Wood and Cellulose (Akad. Nauk SSSR, Moscow, 1962) [in Russian].
V. A. Krakhmalev and A. A. Paiziev, Cellulose, No. 13, 45 (2006).
V. I. Komarov, Deformation and Failure of Fibrous Paper and Pulp Materials (Arkhangelsk. Gos. Tekh. Univ., Arkhangelsk, 2002) [in Russian].
L. A. Alyoshina, N. V. Melekh, and D. V. Loginov, Some Advanced Materials of the Nord-West of the Russian Federation Based on Cellulose, Carbon, and Silicates (Petrozavodsk. Gos. Univ., Petrozavodsk, 2012) [in Russian].
S. V. Frolova and V. A. Demin, in Proceedings of 3 All-Russia Scientific Conference “Progress in Chemistry and Chemical Technology of Vegetable Raw”, Barnaul, 2007, Book 3, p. 247.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.V. Melekh, S.V. Frolova, L.A. Aleshina, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 2, pp. 134–141.
Rights and permissions
About this article
Cite this article
Melekh, N.V., Frolova, S.V. & Aleshina, L.A. X-ray analysis of powdered celluloses obtained with the use of Lewis acids. Polym. Sci. Ser. A 56, 129–136 (2014). https://doi.org/10.1134/S0965545X14020102
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X14020102