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The role of chain structure in the rheological behavior of vinyl acetate-vinyl alcohol copolymers

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Abstract

A comparative study of the viscoelastic properties of melts of vinyl acetate-vinyl alcohol copolymers with equimolar compositions characterized by different statistical distributions of chain units has been performed. It has been shown that the principle of temperature-frequency superposition is obeyed by copolymers close to a random copolymer, but is violated by copolymers with the block distribution of units. Unlike amorphous random copolymers, a multiblock copolymer is characterized by weak crystallinity, the absence of the relaxation flow state, and a more pronounced tendency to form interchain hydrogen bonds both between two hydroxyl groups and between hydroxyl and ester groups.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    S. O. Ilyin, Yu. I. Denisova, L. B. Krentsel’, G. A. Shandryuk, G. N. Bondarenko, A. D. Litmanovich, V. G. Kulichikhin, A. Ya. Malkin & Ya. V. Kudryavtsev

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  1. S. O. Ilyin
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  2. Yu. I. Denisova
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  3. L. B. Krentsel’
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  4. G. A. Shandryuk
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  5. G. N. Bondarenko
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  6. A. D. Litmanovich
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  7. V. G. Kulichikhin
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  8. A. Ya. Malkin
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  9. Ya. V. Kudryavtsev
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Correspondence to S. O. Ilyin.

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Original Russian Text © S.O. Ilyin, Yu.I. Denisova, L.B. Krentsel’, G.A. Shandryuk, G.N. Bondarenko, A.D. Litmanovich, V.G. Kulichikhin, A.Ya. Malkin, Ya.V. Kudryavtsev, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 2, pp. 197–205.

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Ilyin, S.O., Denisova, Y.I., Krentsel’, L.B. et al. The role of chain structure in the rheological behavior of vinyl acetate-vinyl alcohol copolymers. Polym. Sci. Ser. A 56, 196–204 (2014). https://doi.org/10.1134/S0965545X14020060

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  • DOI: https://doi.org/10.1134/S0965545X14020060

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