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Rheological properties of cellulose-chitosan-phosphoric acid systems in different phase states

Polymer Science Series A volume 56, pages 137–145 (2014)Cite this article

Abstract

Rheological properties of 7.0–9.1% cellulose-chitosan suspensions, solutions, and gels in aqueous phosphoric acid were examined in various modes of shear flow in the range 0.15–100 s−1 at 268–323 K. During steady state flow, the appearance of a quasi-Newtonian region was detected at shear rates between 20 and 40 s−1 owing to orientational ordering of macromolecules in the stream. Under the conditions of transient shear flow at a constant shear rate, rheopexy was observed in both cellulose solutions and cellulose-chitosan solutions. The thixotropic behavior of cellulose-chitosan suspensions, spinning solutions, and gels was characterized during a sharp drop of shear rate from 0.15 to 10 s−1, that is, under conditions modeling the processes of transport and extrusion of spinning solutions.

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References

  1. A. N. Gonchar, D. D. Grinshpan, S. E. Makarevich, N. G. Tsygankova, and E. V. Sheimo, Vestn. Belneftekhim. Neftekhim. Kompleks, No. 1 (6), 6 (2011).

    Google Scholar 

  2. D. D. Grinshpan, N. G. Tsygankova, and F. N. Kaputskii, USSR Inventor’s Certificate No. 1348396 (1987).

    Google Scholar 

  3. H. Boerstoel, H. Maatman, J. B. Westerink, and B. M. Koenders, Polymer 42, 7371 (2001).

    Article  CAS  Google Scholar 

  4. M. G. Northolt, H. Boerstoel, H. Maatman, R. Huisman, J. Veurink, and H. Elzerman, Polymer 42, 8249 (2001).

    Article  CAS  Google Scholar 

  5. S. J. Picken, D. J. Sikkema, H. Boerstoel, T. J. Dingemans, and V. Zwaag, Liq. Cryst. 38, 1591 (2011).

    Article  CAS  Google Scholar 

  6. S. Janjic, M. Kostic, V. Vucinic, S. Dimitrijevic, K. Popovic, M. Ristic, and P. Skundric, Carbohydr. Polym. 78, 240 (2009).

    Article  CAS  Google Scholar 

  7. S. Z. Rogovina and G. A. Vikhoreva, Glycoconjug. J. 23, 611 (2006).

    Article  CAS  Google Scholar 

  8. Z. Li, X. P. Zhuang, X. F. Liu, Y. L. Guan, and K. D. Yao, Polymer 43, 1541 (2002).

    Article  CAS  Google Scholar 

  9. C. M. Shih, Y. T. Shieh, and Y. K. Twu, Carbohydr. Polym. 78, 169 (2009).

    Article  CAS  Google Scholar 

  10. X. Duan, J. Xu, B. He, J. Li, and Y. Sun, BioResources 6, 4640 (2011).

    CAS  Google Scholar 

  11. H. Xie, S. Zhang, and S. Li, Green Chem. 8, 630 (2006).

    Article  CAS  Google Scholar 

  12. O. Kuzmina, T. Heinze, and D. Wawro, ISRN Polym. Sci. 2012, Article ID 251950 (2012).

    Google Scholar 

  13. B. Ma, M. Zhang, C. He, and J. Sun, Carbohydr. Polym. 88, 347 (2012).

    Article  CAS  Google Scholar 

  14. D. R. Biswal and R. P. Singh, Inc. J. Appl. Polym. 94, 1480 (2004).

    Article  CAS  Google Scholar 

  15. M. Edali, M. N. Esmail, and G. H. Vatistas, J. Appl. Polym. Sci. 78, 1787 (2001).

    Article  Google Scholar 

  16. D. D. Grinshpan, A. N. Gonchar, N. G. Tsygankova, S. M. Makarevich, T. A. Savitskaya, and E. V. Shejmo, J. Eng. Phys. Thermophys. 84, 594 (2011).

    Article  CAS  Google Scholar 

  17. A. M. Ritcey and D. G. Gray, Biopolymers 27, 1363 (1988).

    Article  CAS  Google Scholar 

  18. V. G. Kulichikhin and L. K. Golova, Khim. Drev., No. 3, 9 (1985).

    Google Scholar 

  19. A. Laszkiewicz, Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 353, 127 (2000).

    CAS  Google Scholar 

  20. L. Schulz, W. Burchard, and R. Donges, Cellul. Derivat., 218 (1998).

    Book  Google Scholar 

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Authors and Affiliations

  1. Research Institute for Physical and Chemical Problems, Belarusian State University, Minsk, 220030, Belarus

    D. D. Grinshpan, A. N. Gonchar, T. A. Savitskaya, N. G. Tsygankova & S. E. Makarevich

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  1. D. D. Grinshpan
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  2. A. N. Gonchar
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  3. T. A. Savitskaya
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  4. N. G. Tsygankova
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  5. S. E. Makarevich
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Correspondence to D. D. Grinshpan.

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Original Russian Text © D.D. Grinshpan, A.N. Gonchar, T.A. Savitskaya, N.G. Tsygankova, S.E. Makarevich, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 2, pp. 142–151.

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Grinshpan, D.D., Gonchar, A.N., Savitskaya, T.A. et al. Rheological properties of cellulose-chitosan-phosphoric acid systems in different phase states. Polym. Sci. Ser. A 56, 137–145 (2014). https://doi.org/10.1134/S0965545X14020059

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  • DOI: https://doi.org/10.1134/S0965545X14020059

Keywords

  • Cellulose
  • Chitosan
  • Shear Rate
  • Polymer Science Series
  • Cellulose Solution