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Temperature dependence of the intrinsic viscosity of poly(methyl methacrylate) in binary solvents used as eluents for liquid chromatography under critical conditions

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Abstract

The effect of temperature on the values of the intrinsic viscosity and swelling degree of poly(methyl methacrylate) macromolecular coils in binary solvents used as eluents for liquid chromatography under critical conditions is studied. It is shown that these values are little temperature-dependent. This circumstance makes it possible to assume that the temperature dependences of retention characteristics are minimally contributed by changes in the dimensions of macromolecules in poly(methyl methacrylate) solutions.

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References

  1. L. S. Litvinova and J. J. Kever, in Proceedings of 6 International Symposium “Molecular Mobility and Order in Polymer Systems”, St. Petersburg, 2008, p. 065.

  2. C. Viet and B. Trathnigg, J. Sep. Sci. 33, 464 (2010).

    Article  Google Scholar 

  3. L. S. Litvinova and N. G. Bel’nikevich, Polym. Sci., Ser. A 52, 1250 (2010).

    Article  Google Scholar 

  4. N. G. Bel’nikevich, L. S. Litvinova, and V. P. Budtov, Russ. J. Appl. Chem. 78, 975 (2005).

    Article  Google Scholar 

  5. G. V. Schuls and U. J. Kantow, J. Polym. Sci. 10, 79 (1953).

    Article  Google Scholar 

  6. V. P. Budtov, Physical Chemistry of Polymer Solutions (Khimiya, St. Petersburg, 1992) [in Russian].

    Google Scholar 

  7. L. Utracry and B. Simha, J. Phys. Chem. 67, 1056 (1963).

    Article  Google Scholar 

  8. R. H. Colby, J. Polym. Sci., Part B: Polym. Phys. 35, 1989 (1997).

    Article  CAS  Google Scholar 

  9. N. Kayaman, E. E. Gürel, B. M. Baysal, and F. E. Karasz, Polymer 41, 1461 (2000).

    Article  CAS  Google Scholar 

  10. M. Doğan and A. Kuntman, Polym. Int. 49, 1648 (2000).

    Article  Google Scholar 

  11. E. E. Gürel, N. Kayaman, B. M. Frank, and F. E. Karasz, J. Polym. Sci., Part B: Polym. Phys. 37, 2253 (1999).

    Article  Google Scholar 

  12. B. M. Baysal and N. Kayaman, J. Chem. Phys. 109, 8701 (1998).

    Article  CAS  Google Scholar 

  13. T. Kawai, J. Appl. Polym. Sci. 3, 227 (1960).

    Article  CAS  Google Scholar 

  14. S. G. Entelis, Sorosovskii Obrazovat. Zh., No. 8, 62 (1996).

    Google Scholar 

  15. L. S. Litvinova, Russ. J. Appl. Chem. 81, 1538 (2008).

    Article  CAS  Google Scholar 

  16. V. P. Budtov, N. G. Bel’nikevich, and L. S. Litvinova, Polym. Sci., Ser. A 52, 362 (2010).

    Article  Google Scholar 

  17. Yu. S. Lipatov and L. M. Sergeeva, Adsorption of Polymers (Naukova Dumka, Kiev, 1972) [in Russian].

    Google Scholar 

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31 (V.O.), St. Petersburg, 199004, Russia

    N. G. Belnikevich, L. S. Litvinova & Z. F. Zoolshoev

Authors
  1. N. G. Belnikevich
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  2. L. S. Litvinova
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  3. Z. F. Zoolshoev
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Correspondence to N. G. Belnikevich.

Additional information

Original Russian Text © N.G. Belnikevich, L.S. Litvinova, Z.F. Zoolshoev, 2014, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2014, Vol. 56, No. 2, pp. 115–120.

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Belnikevich, N.G., Litvinova, L.S. & Zoolshoev, Z.F. Temperature dependence of the intrinsic viscosity of poly(methyl methacrylate) in binary solvents used as eluents for liquid chromatography under critical conditions. Polym. Sci. Ser. A 56, 111–116 (2014). https://doi.org/10.1134/S0965545X14020023

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  • DOI: https://doi.org/10.1134/S0965545X14020023

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