Skip to main content
Log in

New pH-responsive and electroactive composite systems containing hydrogels and conducting polymers on a porous matrix

  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

New types of stimuli responsive composite polymer systems containing electro- and pH-responsive components are prepared. In these systems, the spatial structure of the active component phase is determined by the matrix of porous polyethylene films that play the role of nanosized containers for hydrogels and electroconducting polymers. Effects of the conditions of the synthesis of active components on the electro-physical properties of the composite system, its pH-responsivity, and reversibility of swelling-contraction processes in media with various pH values are investigated. It is shown that the matrix structure affects the magnitude of the response to the external stimuli and the morphological features, swelling ability, electric conductivity, and mechanical behavior of the systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. Yu. Kramarenko, A. E. Philippova, and A. R. Khokhlov, Polymer Science, Ser. C 48, 1 (2006).

    Article  Google Scholar 

  2. S. Chaterji, I. K. Kwon, and K. Park, Prog. Polym. Sci. 32, 1083 (2007).

    Article  CAS  Google Scholar 

  3. F. Horkay, I. Tasaki, and P. Basser, Biomacromolecules 1, 84 (2000).

    Article  CAS  Google Scholar 

  4. T. O. Ali, Surf. Coat. Technol. 200, 3918 (2006).

    Article  Google Scholar 

  5. M. Y. Guo, Y. Wei, A. G. MacDiarmid, and P. I. Lelkers, Biomaterials 27, 2705 (2006).

    Article  Google Scholar 

  6. T. Tanaka, in Encyclopedia of Polymer Science and Engineering (Wiley, New York, 1987), Vol. 7, p. 514.

    Google Scholar 

  7. M. Ilavski, Macromolecules 15, 782 (1982).

    Article  Google Scholar 

  8. T. Ishida, Y. Hasimoto, Y. Iwai, and Y. Arai, Colloid Polym. Sci. 272, 1313 (1994).

    Article  Google Scholar 

  9. G. K. Elyashevich, E. Yu. Rozova, and E. A. Karpov, RF Patent No. 2 140 936 (1997).

  10. G. K. Elyashevich, A. G. Kozlov, and E. Yu. Rozova, Polymer Science, Ser. A 40, 567 (1998).

    Google Scholar 

  11. S. A. Dubrovskii, M. V. Afanas’eva, M. A. Ryzhkin, and K. S. Kazanskii, Vysokomol. Soedin., Ser. A 31, 321 (1989).

    CAS  Google Scholar 

  12. G. K. Elyashevich, N. G. Bel’nikevich, and S. A. Vesnebolotskaya, Polymer Science, Ser. A 51, 550 (2009).

    Article  Google Scholar 

  13. G. K. Elyashevich, M. A. Smirnov, N. V. Bobrova, N. N. Saprykina, and V. Bukošek, in Proceedings of “European Polymer Congress-2009”, Graz, Austria, 2009, p. 241. PC3–50.

  14. N. G. Bel’nikevich, N. V. Bobrova, V. Yu. Elokhovskii, Z. F. Zoolshoev, M. A. Smirnov, and G. K. Elyashevich, Zh. Prikl. Khim. (S.-Peterburg) 84, 2245 (2011).

    Google Scholar 

  15. T. Tanaka, I. Nishio, S. T. Sun, and S. Ueno-Nishio, Science (Washington, D. C.) 218, 467 (1982).

    Article  CAS  Google Scholar 

  16. M. A. Smirnov, N. V. Bobrova, I. Yu. Dmitriev, V. Bukošek, and G. K. Elyashevich, Polymer Science, Ser. A 53, 67 (2011).

    Article  CAS  Google Scholar 

  17. R. Gangopadhyay and A. De, Synth. Met. 132, 21 (2002).

    Article  CAS  Google Scholar 

  18. M. Chakraborty, D. C. Mukherjee, and B. M. Mandal, Synth. Met. 98, 193 (1999).

    Article  Google Scholar 

  19. R. A. Zoppi and M.-A. D. Paoli, Polymer 37, 1999 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to G. K. Elyashevich.

Additional information

Original Russian Text © G.K. Elyashevich, M.A. Smirnov, 2012, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2012, Vol. 54, No. 11, pp. 1675–1684.

This work was supported by the Russian Foundation for Basic Research (project nos. 07-03-00177 and 10-03-00421) and by the Program of Basic Research of the Division of Chemistry and Materials Sciences, Russian Academy of Sciences, for 2009 (direction “Electroconducting and Electroactive Polymers”).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Elyashevich, G.K., Smirnov, M.A. New pH-responsive and electroactive composite systems containing hydrogels and conducting polymers on a porous matrix. Polym. Sci. Ser. A 54, 900–908 (2012). https://doi.org/10.1134/S0965545X12110028

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X12110028

Keywords

Navigation