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Transformation of the modified layer of fluorinated polyolefins under stretching

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Abstract

The stress-strain properties of the fluorinated layer of polyolefin films are estimated. A comparison of the elastic moduli of fluorinated and original film samples of LDPE and HDPE shows that the surfacefluorinated films of polyolefins can be assigned to “rigid coating on a soft support” systems. Deformation of these multilayer films leads to a special type of superficial gelation with a characteristic regular relief. With allowance for this relief, it is possible to calculate the ultimate stress of the fluorinated layer for LDPE and HDPE films.

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Correspondence to V. G. Nazarov.

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Original Russian Text © V.G. Nazarov, A.L. Volynskii, L.M. Yarysheva, V.P. Stolyarov, N.F. Bakeev, 2012, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2012, Vol. 54, No. 9, pp. 1355–1359.

This work was supported by the Russian Foundation for Basic Research (project nos. 10-03-00412a and 11-03-12032-ofi-m) and the Ministry of Education and Science of the Russian Federation within the framework of the federal target program Scientific and Educational Specialists of Innovation Russia for 2009–2013 (State Contract no. 14.740.11.0848).

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Nazarov, V.G., Volynskii, A.L., Yarysheva, L.M. et al. Transformation of the modified layer of fluorinated polyolefins under stretching. Polym. Sci. Ser. A 54, 679–683 (2012). https://doi.org/10.1134/S0965545X12080081

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  • DOI: https://doi.org/10.1134/S0965545X12080081

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