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Influence of sublimation of destruction products on the pattern of DSC thermograms of polymeric materials

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Abstract

Differential-scanning-calorimetry thermograms measured for various polymers (atactic poly(methyl methacrylate), low-density polyethylene, and polytetrafluoroethylene) are analyzed with allowance for simultaneously obtained thermogravimetric-analysis data. Special attention is paid to the interpretation of “false” peaks arising owing to the synchronism of strong endothermic processes of sublimation of destruction products and other thermal processes.

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Authors and Affiliations

  1. Institute of Problems of Mechanical Engineering, Russian Academy of Sciences, Bol’shoi pr. 61 (V.O.), St. Petersburg, 199178, Russia

    B. M. Ginzburg

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  1. B. M. Ginzburg
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Correspondence to B. M. Ginzburg.

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Original Russian Text © B.M. Ginzburg, 2012, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2012, Vol. 54, No. 3, pp. 448–454.

This work was supported by the Russian Foundation for Basic Research (project no. 09-08-01076a) and by the Program of Basic Research of the Division of Energetics, Engineering, Mechanics, and Control Processes, Russian Academy of Sciences (coordinator I.G. Goryacheva).

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Ginzburg, B.M. Influence of sublimation of destruction products on the pattern of DSC thermograms of polymeric materials. Polym. Sci. Ser. A 54, 248–254 (2012). https://doi.org/10.1134/S0965545X12030029

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  • DOI: https://doi.org/10.1134/S0965545X12030029

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