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Proton-conducting gel electrolytes based on poly(methyl methacrylate) doped with phosphoric acid in N,N-dimethylformamide

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Abstract

Time-stable proton-conducting gel electrolytes based on poly(methyl methacrylate) doped by o-phosphoric acid solutions of different concentrations in DMF are prepared. The dependences of the electrical conductivity of the gels on the concentrations of the acid and polymer and the molecular mass of PMMA at 25–65°C are studied. The thermal stability of electrolytes is estimated. It is found that an increase in the content of the polymer in gels changes the thermal behavior of the samples.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya ul. 1, Ivanovo, 153045, Russia

    L. E. Shmukler, L. P. Safonova & M. S. Gruzdev

  2. Ivanovo State University of Chemical Technology, pr. Fridrikha Engel’sa 7, Ivanovo, 153460, Russia

    L. P. Safonova & Nguen Van Thuk

Authors
  1. L. E. Shmukler
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  2. L. P. Safonova
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  3. Nguen Van Thuk
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  4. M. S. Gruzdev
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Corresponding author

Correspondence to L. E. Shmukler.

Additional information

Original Russian Text © L.E. Shmukler, L.P. Safonova, Nguen Van Thuk, M.S. Gruzdev, 2011, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2011, Vol. 53, No. 1, pp. 46–53.

This work was supported by the Russian Foundation for Basic Research, project no. 08-03-00288a.

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Shmukler, L.E., Safonova, L.P., Van Thuk, N. et al. Proton-conducting gel electrolytes based on poly(methyl methacrylate) doped with phosphoric acid in N,N-dimethylformamide. Polym. Sci. Ser. A 53, 44–51 (2011). https://doi.org/10.1134/S0965545X11010056

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  • DOI: https://doi.org/10.1134/S0965545X11010056

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