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Competition between poly(methyl methacrylate) and poly(ethylene glycol) during their interaction with poly(silicic acid) in an organic solvent

Polymer Science Series A volume 52, pages 842–848 (2010)Cite this article

Abstract

It is shown that the interpolymer complex of poly(silicic acid) and poly(ethylene glycol) formed in the organic solvent benzene is thermodynamically more stable than the corresponding complex with PMMA. Therefore, poly(silicic acid) prepared via template polycondensation conducted in the presence of poly(ethylene glycol) contains a smaller amount of defects (branches and crosslinks) than the same polymer obtained in the presence of PMMA. To provide evidence for the interaction between poly(silicic acid) and PMMA, the dynamic light-scattering method with the use of “invisible” macromolecules has been applied for the first time.

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Authors and Affiliations

  1. Moscow State Automobile and Road Technical University, Leningradskii pr. 64, Moscow, 125319, Russia

    I. M. Papisov & V. V. Grushina

  2. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    E. A. Litmanovich

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    D. A. Sapozhnikov & Ya. S. Vygodskii

  4. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571, Russia

    I. A. Gritskova

Authors
  1. I. M. Papisov
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  2. V. V. Grushina
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  3. E. A. Litmanovich
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  4. D. A. Sapozhnikov
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  5. Ya. S. Vygodskii
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  6. I. A. Gritskova
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Correspondence to I. M. Papisov.

Additional information

Original Russian Text © I.M. Papisov, V.V. Grushina, E.A. Litmanovich, D.A. Sapozhnikov, Ya.S. Vygodskii, I.A. Gritskova, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 8, pp. 1451–1457.

This work was supported by the special-purpose agency program Development of the Scientific Potential of the Higher School (2006-2008), project RNP 2.1.1/2159.

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Papisov, I.M., Grushina, V.V., Litmanovich, E.A. et al. Competition between poly(methyl methacrylate) and poly(ethylene glycol) during their interaction with poly(silicic acid) in an organic solvent. Polym. Sci. Ser. A 52, 842–848 (2010). https://doi.org/10.1134/S0965545X10080110

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  • DOI: https://doi.org/10.1134/S0965545X10080110

Keywords

  • PMMA
  • Polymer Science Series
  • Polycondensation
  • Silicic Acid
  • Replacement Reaction