Skip to main content
SpringerLink
Log in

Structural and morphological features of organic-inorganic hybrid materials based on ethoxysilanes and epoxy resin

  • Composites
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

The structure of epoxy-silica nanocomposites prepared by the sol-gel method via the cationic polymerization of the organic component and anhydride curing was studied by small-angle X-ray scattering. In the presence of 1.5% silica in the epoxy polymer, mass-fractal aggregates of the inorganic component are formed. In the range of low and high concentrations of SiO2, microphase segregation with the separation of inclusions randomly distributed in the epoxy matrix occurs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Mascia, L. Prezzi, and B. Haworth, J. Mater. Sci. 41, 1145 (2006).

    Article  CAS  Google Scholar 

  2. W. Araki, Sh. Wada, and T. Adachi, J. Appl. Polym. Sci. 108, 2421 (2008).

    Article  CAS  Google Scholar 

  3. L. Mat jka, J. Pleštil, and K. Dušek, J. Non-Cryst. Solids 226, 114 (1998).

    Article  Google Scholar 

  4. L. A. Savenkova, V. M. Mikhal’chuk, V. I. Rybachenko, et al., Vopr. Khim. Khim. Tekhnol., No. 1, 117 (2007).

  5. S. V. Zhil’tsova, V. M. Mikhal’chuk, E. M. Petrova, et al., Russ. J. Appl. Chem. 80, 477 (2007).

    Article  Google Scholar 

  6. S. V. Zhil’tsova, V. M. Mikhal’chuk, V. A. Beloshenko, and A. V. Kirilash, Zh. Prikl. Khim. (St. Petersburg) 82, 676 (2009).

    Google Scholar 

  7. N. Grossiord, J. Loos, L. Van Laake, et al., Adv. Funct. Mater. 18, 3226 (2008).

    Article  CAS  Google Scholar 

  8. Chemist’s Handbook: General Properties of Inorganic and Organic Compounds, Ed. by B. P. Nikol’skii (Goskhimizdat, Moscow, 1963), Vol. 2 [in Russian].

    Google Scholar 

  9. Yu. S. Lipatov, V. V. Shilov, Yu. P. Gomza, and N. E. Kruglyak, X-Ray Methods for Studying Polymer Systems (Naukova Dumka, Kiev, 1982) [in Russian].

    Google Scholar 

  10. C. G. Vonk, J. Appl. Crystallogr. 8, 340 (1974).

    Article  Google Scholar 

  11. V. M. Luk’yanovich, Electron Microscopy in Physicochemical Investigations. Methods and Applications (Akad. Nauk SSSR, Moscow, 1960) [in Russian].

    Google Scholar 

  12. A. P. Shpak, V. V. Shilov, O. A. Shilova, and Yu. A. Kunitskii, Diagnostics of Nanosystems. Multilevel Fractal Structures (Tekhnicheskii Tsentr Akad. Nauk Ukrainy, Kiev, 2004) [in Russian].

    Google Scholar 

  13. C. J. Brinker and G. W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Process (Academic, San Diego, 1990).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Polymer Physics, Institute of Macromolecular Chemistry, National Academy of Sciences of Ukraine, Khar’kovskoe sh. 48, Kiev, 02160, Ukraine

    Yu. P. Gomza & V. V. Klepko

  2. Faculty of Chemistry, Donetsk National University, Universitetskaya ul. 24, Donetsk, 83001, Ukraine

    S. V. Zhil’tsova, V. M. Mikhal’chuk & L. A. Savenkova

  3. Department of Physical Materials Science, Donetsk Institute of Physics and Engineering, National Academy of Sciences of Ukraine, ul. Rozy Lyuksemburg 72, Donetsk, 83114, Ukraine

    T. E. Konstantinova

  4. Department of Technological Research of Hydropressing Processes, Donetsk Institute Physics and Engineering, National Academy of Sciences of Ukraine, ul. Rozy Lyuksemburg 72, Donetsk, 83114, Ukraine

    V. A. Beloshenko

Authors
  1. Yu. P. Gomza
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Klepko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Zhil’tsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. M. Mikhal’chuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. L. A. Savenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. T. E. Konstantinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. A. Beloshenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Zhil’tsova.

Additional information

Original Russian Text © Yu.P. Gomza, V.V. Klepko, S.V. Zhil’tsova, V.M. Mikhal’chuk, L.A. Savenkova, T.E. Konstantinova, V.A. Beloshenko, 2010, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2010, Vol. 52, No. 6, pp. 963–968.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gomza, Y.P., Klepko, V.V., Zhil’tsova, S.V. et al. Structural and morphological features of organic-inorganic hybrid materials based on ethoxysilanes and epoxy resin. Polym. Sci. Ser. A 52, 628–632 (2010). https://doi.org/10.1134/S0965545X1006009X

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X1006009X

Keywords

Search

Navigation